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乳化脱脂及硅烷化封闭对樟子松木材表面性能的影响

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采用不同质量浓度的月桂醇聚醚硫酸脂钠(AES)复配乳液对樟子松木材进行蒸煮脱脂后,用水解不同时间的甲基三甲氧基硅烷(MTMS)溶液对脱脂材进行封闭处理,测定木材的脱脂率和溢脂率,分析素材、脱脂材和脱脂-封闭材的表面化学结构、润湿性及力学性能.结果表明:脱脂率随AES浓度的增加而增加,当AES浓度为2.5%时,脱脂率达39.0%,溢脂率仅为1.0%;脱脂-封闭材表面出现了低表面能的Si-CH3特征吸收峰,其表面水和油的接触角大小、静置稳定性随MTMS水解时间的延长而提高;脱脂-封闭材的24h吸水率[(51±4)%]显著小于素材[(60±5)%],顺纹抗压强度与素材相比略有增加.
Effect of Emulsion Degreasing and Silanization Sealing on the Surface Properties of Pinussylvestris var.mongolica Wood
The Pinussylvestris var.mongolica wood was degreased by cooking with different mass concentra-tions of sodium laureth sulfate(AES)compound emulsion,and then the degreased wood was closed with methyl-trimethoxysilane(MTMS)solution hydrolyzed for different time.The degreasing rate and overflow rate were measured,and the surface chemical structure,wettability,and mechanical properties of control,degreased and de-greased-closed wood were analyzed.The results showed that the degreasing rate increased with the increase of AES concentration.When the AES concentration was 2.5%,the degreasing rate reached 39.0%,and the fat spillage rate was only 1.0%.Low surface energy Si-CH3 characteristic absorption peaks appeared on the surface of the degreased-closed wood,and the contact angle between water and oil on the surface as well as the static sta-bility increased with the increase of the hydrolysis time of MTMS.The 24 h water absorption of degreased-closed wood,which was(60±5)%,decreased significantly compared with the control wood,which was(51±4)%,and the compressive strength parallel to the grain increased slightly.

Pinus sylvestris var.mongolicawoodemulsified degreasingmethyltrimethoxysilanewettabil-itymechanical property

于新栋、孙永平、柴希娟、徐开蒙、解林坤

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西南林业大学材料与化学工程学院,云南 昆明 650233

西南林业大学云南省木材胶黏剂及胶合制品重点实验室,云南 昆明 650233

樟子松 木材 乳化脱脂 甲基三甲氧基硅烷 润湿性 力学性能

2024

西南林业大学学报
西南林业大学

西南林业大学学报

CSTPCD北大核心
影响因子:0.773
ISSN:2095-1914
年,卷(期):2024.44(11)