刑事技术2024,Vol.49Issue(1) :85-92.DOI:10.16467/j.1008-3650.2023.0037

基于GC-MS技术的化学计量学方法鉴别酱香型白酒初探

Preliminary Authentication Analysis of Moutai-flavor Liquor by Gas Chromatography-mass Spectrometry Coupled with Chemometrics

张健 尹宝华 廉哲 王蔚昕 李志豪 邹积鑫 石高军
刑事技术2024,Vol.49Issue(1) :85-92.DOI:10.16467/j.1008-3650.2023.0037

基于GC-MS技术的化学计量学方法鉴别酱香型白酒初探

Preliminary Authentication Analysis of Moutai-flavor Liquor by Gas Chromatography-mass Spectrometry Coupled with Chemometrics

张健 1尹宝华 1廉哲 1王蔚昕 1李志豪 1邹积鑫 1石高军1
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作者信息

  • 1. 公安部鉴定中心,北京 100038
  • 折叠

摘要

近年来假冒酱香型白酒(主要为茅台酒)的案件频发,严重扰乱市场经济秩序,因此实现假冒酱香型白酒的鉴别具有重要意义.本研究建立了基于GC-MS技术与化学计量学相结合的方法,用于酱香型白酒的真假鉴别和案件串并.主成分分析(PCA)对不同来源的酱香型白酒样品实现了鉴别分类,偏最小二乘判别分析(PLS-DA)和聚类分析热图(Heatmap)将区分样品的化学标志物筛选出来.研究表明,GC-MS技术结合化学计量学在源头追踪和案件关联方面具有巨大潜力,可以为打击假冒白酒案件犯罪提供技术支持.

Abstract

In recent years,there have been several cases of fake Moutai-flavor liquor(mainly Moutai),which has seriously disrupted the market economic order,so it is of great significance to realize the identification of fake Moutai-flavor liquor.In this study,the gas chromatography-mass spectrometry(GC-MS)technology coupled with chemometrics was established to identify shoddy products and case combinations.Principal component analysis(PCA)was used to identify the Moutai-flavor liquor samples from different sources.Chemical markers,contributing to authentication,were screened by the partial least squares-discriminant analysis(PLS-DA)and heatmap visualization.This study shows that GC-MS coupled with chemometrics has great potential in source tracing and case linking,thus providing technical support for combating the crime of fake Moutai-flavor liquor cases.

关键词

理化检验/酱香型白酒/气相色谱-质谱/化学计量学/化学标志物/源头追溯

Key words

physical and chemical test/Moutai-flavor liquor/gas chromatography-mass spectrometry(GC-MS)/chemometrics/chemical markers/source tracing

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基金项目

中央级公益性科研院所基本科研业务费专项资金项目(2021JB027)

出版年

2024
刑事技术
公安部物证鉴定中心

刑事技术

CSTPCD
影响因子:0.315
ISSN:1008-3650
参考文献量11
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