首页|三种β-取代茚三酮的合成及显现汗潜手印的研究

三种β-取代茚三酮的合成及显现汗潜手印的研究

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本文基于傅克酰基化取代反应合成了三种茚三酮类似物:β-甲氧基茚三酮、β-硝基茚三酮、β-甲基茚三酮,比较并研究相同配方下三种β-取代茚三酮在不同纸张上显现汗潜手印的效果,并分别与茚三酮进行比较,分析其优劣.结果显示,三种β-取代茚三酮的显现液基本可显示不同纸张上的新鲜指纹,但β-硝基茚三酮对于陈旧指纹的显现效果较差,且显现液本身为棕褐色,显示出的指纹纹线为黑褐色,故视觉感官上稍劣于其他两者;β-甲氧基茚三酮和β-甲基茚三酮的效果均与茚三酮相当,灵敏度略高于茚三酮,显色后的稳定性高于茚三酮.研究表明,β-位取代基的变化能够改变茚三酮类化合物显现手印的效果,给电子基团的修饰能够提高该类化合物的手印显现性能,化合物本身的荧光性能与实际的指纹显现效果并不直接相关.
Three β-substituted Ninhydrin Derivatives:Synthesis and Study on the Development of Latent Fingerprints
The synthesis of three β-substituted ninhydrin derivatives and their application to the development of latent fingerprints on paper surfaces were investigated.Under the same concentration,the effects of β-OMe,β-NO2,β-Me ninhydrin were compared through latent fingerprint developments on different papers with multiple dimensions,respectively,and their effects were also compared with ninhydrin to analyze the advantages and disadvantages.Three β-substituted ninhydrin derivatives could develop fingerprints on different papers.The effect of β-NO2 ninhydrin was slightly inferior to the others as its solution was brown at the same time the displayed fingerprint was dark brown;the effect of β-OMe,β-Me ninhydrin was equivalent to ninhydrin in many dimensions and the sensitivity was slightly higher than ninhydrin,as well as the stability of Ruhemann's purple.The modification on β-position could change the fingerprint development effect of ninhydrin;the substitution of electron-donating groups could improve the fingerprint development effect of ninhydrin;the fluorescence performance of these compounds was not directly related to the visual effect of fingerprint display.

latent fingerprint developmentsemi-porous and porous surfaceβ-substituted ninhydrin

张岩峰、郭先超、马荣梁、孙振文、耿松、王铭兆

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四川警察学院刑事技术系,智能警务四川省重点实验室,四川泸州 646000

四川省成都市金堂县公安局,成都 610499

公安部鉴定中心,痕迹科学与技术公安部重点实验室,北京 100038

公安部刑事侦查局刑事技术处,北京 100741

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手印显现 渗透/半渗透客体 β-取代茚三酮

痕迹科学与技术公安部重点实验室开放基金刑事检验四川省高等学校重点实验室开放基金智能警务四川省重点实验室开放基金

2020FMKFKT032021YB03ZNJW2023ZZMS003

2024

刑事技术
公安部物证鉴定中心

刑事技术

CSTPCD
影响因子:0.315
ISSN:1008-3650
年,卷(期):2024.49(2)
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