湘潭大学学报(自然科学版)2024,Vol.46Issue(1) :58-69.DOI:10.13715/j.issn.2096-644X.20230306.0003

基于质子膜的尿残液膜蒸馏影响因素研究

Factors influencing the membrane distillation of urine brine using on ionomer membranes

张非凡 张良长 薛玉荣 李森 田科 吴志强
湘潭大学学报(自然科学版)2024,Vol.46Issue(1) :58-69.DOI:10.13715/j.issn.2096-644X.20230306.0003

基于质子膜的尿残液膜蒸馏影响因素研究

Factors influencing the membrane distillation of urine brine using on ionomer membranes

张非凡 1张良长 2薛玉荣 1李森 2田科 3吴志强2
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作者信息

  • 1. 湘潭大学环境与资源学院,湖南湘潭 411105;中国航天员科研训练中心,北京 100094
  • 2. 中国航天员科研训练中心,北京 100094
  • 3. 湘潭大学环境与资源学院,湖南湘潭 411105
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摘要

针对尿残液强酸强腐蚀性、物质含量高的特点,开发以质子膜为介质的间接加热气扫式膜蒸馏技术,完成尿残液的水分回收,以进一步提高空间站环控生保系统水资源闭合度.对比研究了 7种质子膜材料的气相和液相两种接触模式下的蒸馏速率,获得质子膜材料的主动吸水、水分传输和尿残液耐受能力等特性.建立了尿残液液相接触模式下的传质传热理论模型,考察了质子膜厚度、尿残液物质浓度、进气流量、进气湿度和进气温度等5个主要变量对蒸馏速率的影响规律,其中进气湿度对蒸馏速率有着相对较大的影响.理论计算所得蒸馏速率与实测值之间的相对标准偏差为5.8%,验证了模型的有效性.研究结果为尿残液水分回收技术的开发和应用提供了理论和实验依据.

Abstract

Water recovery from urine brine is vital to improving water closure in the environmental control and life support system of the space station.Considering the unique properties of high acidity,strong corro-sion and complex composition of urine brine,we have developed indirect heated sweeping gas membrane dis-tillation technology with a ionomer membrane as medium.In this study,distillation rates of seven proton membrane materials under two contact modes of gas phase and liquid phase were obtained to compare their capacity for active water adsorption,water transport and urine brine tolerance.A theoretical model of mass and heat transfer was established under the mode of liquid phase contact of urine brine to investigate the in-fluence of five main factors on the distillation rate,including membrane thickness,urine brine concentra-tion,inlet air flow,inlet air humidity and inlet air temperature.Consequently,the inlet air humidity posed a stronger impact on the distillation rate.The relative standard deviation between the calculated distillation rate and the measured value was 5.8%,which verified the validity of the theoretical model.These results will provide a theoretical and experimental guidance for the development and application of water recovery technology for urine brine.

关键词

质子膜/传热传质/环控生保/尿处理

Key words

ionomer membrane/heat and mass transfer/environmental control and life support system/u-rine treatment

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基金项目

人因工程重点实验室稳定支持项目(GJSD18001)

出版年

2024
湘潭大学学报(自然科学版)
湘潭大学

湘潭大学学报(自然科学版)

CSTPCD
影响因子:0.403
ISSN:2096-644X
参考文献量24
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