Estimation for Thermodynamic Data of Metal Thiourea Complexes
It lacks of thermodynamic data because of the complexity of structure and variety on metal thiourea complexes,which makes it difficult to carry out thermodynamic analysis.Metal thiourea complexes are considered to be composed of simple organic compound and ions in this paper.Standard molar heat capacities of metal thiourea complexes,simple organic compound and ions are calculated by PeHbo equation,Misenrd method and D.F.Taylor method.Standard molar formation entropies of metal thiourea complexes are calculated by гepцa equation.Standard molar formation free energies of metal thiourea complexes are calculated according to standard molar formation enthalpies of simple organic compound and ions and the calculated standard molar formation entropy.Estimation for thermodynamic data of metal thiourea complexes can provide the theoretical fundamentals for the application of thermodynamic analysis in the field of metal thiourea complexes.
metal thiourea complexesstandard molar formation free energy of formationthermodynamic dataestimation
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