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低阶煤基炭材料研究进展

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低阶煤因其储量丰富、富含多环芳烃有机物、含碳量高、成本低等特点,被认为是炭材料的优质前驱体.然而,由于不同低阶煤的灰分、微观结构、界面的差异,导致了煤基炭材料结构、性能难以有效调控的问题.近年来,研究人员提出了低阶煤基炭材料微观结构、表界面调控的有效方法.本文重点总结了低阶煤制备吸附活性炭、电容炭、硬炭、石墨和纳米炭材料的差异化策略,进一步讨论了煤种和工艺对煤基炭材料的微观结构、界面特性和官能团种类等的影响.同时介绍了煤基炭材料在吸附、超级电容器和碱金属电池中的应用.最后,展望了低级煤基炭材料未来研究的方向和挑战.
A review of low-rank coal-based carbon materials
Low-rank coals are highly regarded as valuable precursors for carbon materials because of their ample reserves,high levels of polycyclic aromatic hydrocarbons,substantial carbon content and cost-effectiveness.Nevertheless,challenges in precisely manipulating the structure and characteristics of carbon materials derived from low-rank coals stem from the differences in ash content,microstructure,and interfaces across various low-rank coal sources.Recent research has provided strategies for governing the microstructure and surface attributes of carbon materials derived from low-rank coals.This review provides an overview of strategies for the preparation of adsorption active carbon,capacitive carbon,hard carbon,graphite and nano-carbon materials from low-rank coals.It also examines the influence of coal type and processing techniques on the microstructure,interface properties and functional group in them.The applications of coal-derived carbon materials in adsorption,supercapacitors,and alkali metal batteries are explored,and potential avenues for future research and its challenges are considered.

Low-rank coalCapacitive carbonHard carbonCoal based graphiteActivated carbon translation

宋文革、曾红久、王斌、黄显虹、李晓明、孙国华

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国能神东煤炭集团有限责任公司,内蒙古鄂尔多斯 017200

中国神华能源股份有限公司,神东煤炭分公司,陕西神木 719315

中国科学院山西煤炭化学研究所,中国科学院炭材料重点实验室,山西太原 030001

低阶煤 电容炭 硬炭 煤基石墨 活性炭

国家自然科学基金资助项目国家自然科学基金资助项目山西省自然科学基金山西省重点研发计划项目中国神华能源股份有限公司神东煤炭分公司科技创新项目

223791572217913920210302124101202202040201007E210100265

2024

新型炭材料
中国科学院山西煤炭化学研究所

新型炭材料

CSTPCD北大核心
影响因子:0.685
ISSN:1007-8827
年,卷(期):2024.39(4)