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铅、镉、砷复合污染土壤修复技术研究进展与展望

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随着工业、农业、采矿业和城市化的快速发展,大量重金属等污染物进入土壤环境系统,由此引发的土壤重金属复合污染问题备受关注。全面掌握重金属复合污染现状、污染特征及修复技术手段,对重金属污染防治和士壤的安全利用具有重要意义。综述了Pb,Cd,As复合污染士壤现状,阐述了污染来源及在土壤中的分布特征与迁移转化特征;归纳总结了物理修复法、固化/稳定化修复法和生物修复法在Pb,Cd,As复合污染治理方面的研究进展;论述了对各种土壤修复技术的优缺点和适用场景,并对未来发展方向进行了展望。相较而言,固化/稳定化修复技术因处理效率高、成本低廉、施工简单等优点成为国内外复合污染土壤修复的主流技术。同时,中国金属矿山规模化消纳需求迫切,综合地区特色利用当地矿山固废研发新的固化/稳定化材料治理Pb,Cd,As复合污染土壤已成为目前固化/稳定化技术领域重点研究方向之一。
Research Progress in Soil Remediation of Lead,Cadmium and Arsenic Pollution
With the rapid development of industry,agriculture,mining and urbanization,a large number of heavy metals and other pollutants enter the soil environmental system,and the combined pollution of heavy metals in soil caused by this problem has attracted much attention.According to the 2014 National Soil Pollution Status Report,19.4%of China's arable land has exceeded the standard for heavy metal pollutants such as Pb,Cd and As,with the sites exceeding the standard for these three typical heavy metals ranking at the top,resulting in a polluted area of over 50 million acres.Soil heavy metal pollution is characterized by long-term persistence,durability,and difficulty in degradation.Through surface and subsurface runoff,it can be transferred from the soil to surrounding water bodies,exacerbating water heavy metal pollution.At the same time,heavy metals in land and water can be absorbed by crops,entering the food chain and accumulating in organisms,causing significant harm to human health.Pb has irreversible effects on the nervous system and children's intellectual development.Cd is a highly toxic heavy metal,long-term exposure to cadmium-contaminated environments may lead to diseases such as kidney damage,osteoporosis,and cancer.As is associated with health issues including cancer,skin diseases,and cardiovascular diseases.However,the coexistence of heavy metals such as Pb,Cd and As in soil in composite pollution poses greater environmental hazards compared to single pollution.Therefore,it is of great significance to comprehensively understand the current situation,characteristics,and remediation technologies of heavy metal composite pollution for the prevention and control of heavy metal pollution and the safe utilization of soil.This review provides a comprehensive overview of the current status,sources of pollution,and distribution and migration characteristics of Pb,Cd and As in soils affected by composite pollution.It particularly emphasized the impact of soil pH,redox potential(Eh),soil organic matter(SOM)and soil types on the migration and transformation of Pb,Cd and As.The study presented a summary of the research progress in the remediation of Pb,Cd and As composite pollution using physical remediation methods,solidification/stabilization techniques,and bioremediation approaches.It discussed the advantages,disadvantages,and applicability of various soil remediation technologies and provides an outlook on future development directions.Specifically,the ex-situ soil washing method had a fast remediation rate but was expensive,easily disrupts soil structure,and might cause secondary pollution.The electrokinetic remediation method had simple equipment operation but was relatively costly,consumed a significant amount of energy,and might pose safety hazards.The bioremediation method could improve soil quality and maintain ecological balance but had a slow remediation process and is highly influenced by the environment.The solidification/stabilization techniques had become the mainstream technology for the remediation of composite pollution in soils due to their high efficiency,low cost,and easy implementation.Furthermore,due to the pressing demand for the large-scale disposal of metal mine wastes in China,the research on developing new solidification/stabilization materials utilizing local mining solid wastes for the remediation of Pb,Cd and As composite polluted soils would become a key focus in the field of solidification/stabilization technologies.

compound pollutionsoil remediationsolidification/stabilizationsolid waste resourceization

孙英春、崔兴兰、郑鹏、史新悦、李红霞、王雷、俞泽恩、郑其

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中国有研科技集团有限公司高品质有色金属绿色特种冶金国家工程研究中心,北京 101407

有研资源环境技术研究院(北京)有限公司,北京 101407

北京有色金属研究总院,北京 100088

战略性有色金属绿色制造技术北京市工程研究中心,北京 101407

有研工程技术研究院有限公司,北京 101407

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复合污染 土壤修复 同化/稳定化 固废资源化

国家重点研发计划项目国家自然科学基金面上基金项目广西重点研发计划项目广西重点研发计划项目

2020YFC1807702522742722022AB260372021AB25065

2024

稀有金属
北京有色金属研究总院

稀有金属

CSTPCD北大核心
影响因子:1.483
ISSN:0258-7076
年,卷(期):2024.48(9)