首页|电火花沉积反应合成TiN增强Fe基金属陶瓷涂层

电火花沉积反应合成TiN增强Fe基金属陶瓷涂层

Reaction Synthesis of TiN Reinforced Fe-Based Metal Matrix Composite Coating by ESD

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利用自制的电火花沉积充气密闭式保护装置和DZ-1400型电火花沉积/堆焊机,以工业纯钛TA2为电极,以工业纯氮为保护气和反应气,在45#钢基体试样表面制各出了厚度为60~80 μm的TiN增强金属基陶瓷涂层.采用扫描电镜(SEM)观测了涂层微观结构和界面行为,分析了涂层形成机理,利用X射线仪(XRD)测定了涂层的物相组成,利用显微硬度仪测试了涂层的显微硬度,利用自制磨损试验机对比了涂层与淬火W18Cr4V高速钢的耐磨性.结果表明:涂层主要由TiN和FeTi两相组成,涂层组织致密、均匀、较连续,涂层与基体形成良好的冶金结合,涂层显微硬度HV高达15.88 GPa,约是基体硬度的5倍,涂层具有较好的耐磨性.
Electric-spark deposition (ESD),which is a micro-welding process,was adopted for depositing a TiN reinforced Fe-based metal matrix composite coating with the thickness of 60~80 μm on 45# steel substrate using a laboratory-developed special gas-filled-closed electric-spark deposition device and elctric-spark deposition machine modeled DZ-1400,where the industry pure titanium (TA2) is used for electrode and the industry pure nitrogen gas as shielding and reacting atmosphere.The microstructures,interfacial behavior and phase of the coatings were investigated by scanning electronic microscope and X-ray diffractometer.The microhardness profile of coatings was tested and its wear-resisting property was compared with that of W18Cr4V rapid steel quenched by the home-made abrasion machine as well.The results show that an excellent bonding between the coatings and carbon steel substrate is ensured by the strong metallurgical interface and phase of the coatings are mainly composed of TiN and FeTi.The highest microhardness HV of coating reaches 15.88 GPa,which is about five times more than that of the substrates.The anti-abrasive test results show the coating has better anti-abrasive performance than W18Cr4V rapid steel treated by quenching.

electric-spark depositionreaction synthesisTiNmetal matrix composite coating

郝建军、卜志国、樊云飞、白庆华、赵建国、李建昌

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河北农业大学,河北,保定,071001

电火花沉积 反应合成 TiN 金属基陶瓷涂层

河北省自然科学基金

E2007000566

2009

稀有金属材料与工程
中国有色金属学会,中国材料研究学会,西北有色金属研究院

稀有金属材料与工程

CSTPCDCSCD北大核心SCIEI
影响因子:0.634
ISSN:1002-185X
年,卷(期):2009.38(z1)
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