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玻璃形成能力及稳定性三角形判定准则

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根据降温过程的玻璃形成能力(GFA)和升温过程的玻璃稳定性(GS),构建了以伪四特征参数组合为顶点的判定玻璃形成能力和稳定性的三角形(Tri-FAS),从而推导出判定GFA&GS的准则:G-FAS=Tg/T+Tx/Tl+Tx/Tg(T为起始结晶温度;Tl为液体温度;Tg为玻璃化转变温度),并从降温过程非晶化与晶化之间的竞争关系和准则各组成项对准则的均衡贡献两个方面进行了修订:G-FASm=Tg/(1.5Tx)+T/Tl+Tx/Tg和 G-FASm'=Tg/Tl+Tx/Tl+(Tx/Tgg)a(a≈1.5±0.2).讨论了 G-FAS 与临界冷却速率Rc、G-FAS 与 Txg(Txg反映了玻璃的过冷液区,Tx=rx/Tg)的相关性,分别能够反映GFA和GS.通过大量金属玻璃和其他玻璃形成体从GFA和GS两方面对判定准则的有效性进行了评估,结果显示:该判定准则无论是GFA方面还是GS方面,在不同玻璃形成体系中均可靠有效,具有广泛应用性.提出的Tri-FAS和G-FAS判定准则在玻璃的生产和实际应用过程中具有指导作用.
Triangle Criterion of Glass-Forming Ability and Stability for Metallic Glasses
Based on the glass-forming ability(GFA)during cooling process and the glass stability(GS)of heating process,a triangle to evaluate GFA and GS,namely Tri-FAS,with the combination of pseudo-four characteristic parameters as vertices was established.Accordingly,a GFA&GA criterion(G-FAS)was deduced as G-FAS=Tg/Tl+Tx/Tl+Tx/Tg(Tx is onset crystallization temperature;Tl is liquid temperature;Tg is glass transition temperature).Additionally,the criterion was modified based on the competitive relationship between amorphous phase and crystal phase during cooling process and the contribution of each component to the criterion:G-FASm=Tg/(1.5Tx)+Tx/T+Tx/Tg and G-FASm'=Tg/Tl+Tx/Tl+(Tx/Tg)a(a≈1.5±0.2).The correlation between G-FAS and critical cooling rate Rc and that between G-FAS and Txg(Txg reflects the supercooled liquid region of glass,Txg=Tx/Tg)were discussed,which could reflect GFA and GS,respectively.Through the determination results of GFA and GS of abundant metallic glasses and other glass formers,the validity of the proposed G-FAS criterion was evaluated.Results show that with respect to both GFA and GS,the G-FAS criterion is reliable in various glass former systems,showing wide applications.The proposed Tri-FAS and G-FAS criterion can provide guidance during the fabrication and application of metallic glasses.

metallic glassesglass-forming abilitythermal stabilitycharacteristic temperaturecriterion

李晓诚、寇生中、赵燕春、李春燕、李春玲

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兰州理工大学材料科学与工程学院,甘肃兰州 730050

兰州理工大学省部共建有色金属先进加工与再利用国家重点实验室,甘肃兰州 730050

兰州理工大学机电工程学院,甘肃兰州 730050

金属玻璃 玻璃形成能力 热稳定性 特征温度 准则

National Natural Science Foundation of ChinaKey Research and Development Program of Gansu Province

5197110320YF8GA052

2024

10.12442/j.issn.1002-185X.E20230034

稀有金属材料与工程
中国有色金属学会,中国材料研究学会,西北有色金属研究院

稀有金属材料与工程

CSTPCD北大核心
影响因子：0.634
ISSN：1002-185X
年,卷(期)：2024.53(1)
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