首页|几种合金在450 ℃/23 MPa超临界水氧化环境中腐蚀行为研究

几种合金在450 ℃/23 MPa超临界水氧化环境中腐蚀行为研究

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采用X射线衍射仪、扫描电子显微镜等分析手段,对比研究了 4种典型镍基耐蚀合金在450 ℃/23 MPa下Na3PO4、Na2SO4、NaCl超临界水溶液中的腐蚀行为.结果表明,50 h后,合金表层均匀分布着短棒状、针状的腐蚀产物,主要组成为NiCr2O41 Cr2O3,NiO,Ni3(PO4)2,CrPO4和Na3PO4等.500 h后,腐蚀层的厚度明显增大,依据腐蚀层厚度的增大速度,4种合金的耐蚀性顺序为:X-1#>X-2#>625>C-276.
Corrosion Behavior of Several Alloys in Supercritical Water Oxidation Environment at 450 ℃/23 MPa
The corrosion behavior of four typical Ni-based corrosion-resistant alloys in supercritical aqueous solution containing Na3PO4,Na2SO4,and NaCl at 450 ℃/23 MPa was studied by XRD,SEM,etc.The results show that after corrosion for 50 h,the surface of the alloys is covered by short rod-shaped and needle-shaped products mainly consisting of NiCr2O4,Cr203,NiO,Ni3(PO4)2,CrPO4,and Na3PO4.With prolonging the time,the thickness of the corrosion layers is increased and the corrosion resistance is ranked as X-1#>X-2#>625>C-276.

nickel-based alloysupercritical water oxidationcorrosion behavior

王琳琳、侯坤磊、查向东、欧美琼、马颖澈

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东北大学材料科学与工程学院,辽宁沈阳 110819

中国科学院金属研究所,辽宁沈阳 110016

镍基合金 超临界水氧化 腐蚀行为

2024

稀有金属材料与工程
中国有色金属学会,中国材料研究学会,西北有色金属研究院

稀有金属材料与工程

CSTPCD北大核心
影响因子:0.634
ISSN:1002-185X
年,卷(期):2024.53(1)
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