首页|Ta、Co对新型高强抗热腐蚀镍基单晶高温合金组织稳定性的影响

Ta、Co对新型高强抗热腐蚀镍基单晶高温合金组织稳定性的影响

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研究了 Ta、Co对一种新型高强抗热腐蚀单晶高温合金微观组织及1000 ℃长期时效中组织稳定性的影响.结果表明,随Ta含量的增加,γ'相溶解温度提高,完全热处理后的γ'相尺寸先增大后减小,Co降低了 γ'相溶解温度,减小了 γ'相尺寸并且降低了 γ'相的含量;1000 ℃长期时效过程中,随Ta含量的提高,γ'相粗化速率先降低后升高,Co降低了 γ'相的粗化速率,γ/γ'两相错配度和元素的扩散是影响γ'相粗化速率的主要因素;Ta提高了合金中γ'相的含量,促使Re、W、Mo、Cr元素向γ基体中分配,促进了 tcp相的析出,Co降低了 Re、W、Mo、Cr元素在γ基体中的分配,降低了基体的过饱和度,抑制了tcp相的析出.
Effects of Ta and Co on Microstructural Stability of Novel High Strength and Hot-Corrosion Resistant Nickel Based Single Crystal Superalloys
The microstructure of hot-corrosion resistant single crystal superalloy with different Ta and Co contents and the microstructure stability during long-term aging at 1000 ℃ was investigated.The results show that in the single crystal superalloy of the experiment,the dissolution temperature of γ'phase increases with the increase in Ta content,the size of γ'phase first increases and then decreases after complete heat treatment.The dissolution temperature of γ'phase decreases and the size of γ'phase and the content of γ'phase reduce with the increase in Co content.During the long-term aging process at 1000 ℃,the coarsening rate of γ'phase first decreases and then increases with the increase in Ta content,while the coarsening rate of γ'phase decreases with the increase in Co content.The mismatch degree of γ/γ'phase and the diffusion of elements in matrix are the main factors affecting the coarsening rate of γ'phase in the four alloys.In addition,Ta increases the content of γ'phase,promotes the distribution of Re,W,Mo and Cr toward γ matrix,and promotes the precipitation of tcp phase,while Co reduces the distribution of Re,W,Mo and Cr in y matrix,reduces the supersaturation of matrix and inhibits the precipitation of tcp phase.

TaCohot-corrosion resistant single crystal superalloymicrostructural stability

来永军、宁礼奎、赵岭、柳一川、刘恩泽、谭政、李海英、佟健、郑志

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中国科学院金属研究所,辽宁 沈阳 110016

中国科学技术大学材料科学与工程学院,辽宁沈阳 110016

中国机械总院集团沈阳铸造研究所有限公司,辽宁 沈阳 110016

Ta Co 抗热腐蚀 单晶高温合金 组织稳定性

国家重点研发计划辽宁省科技攻关计划

2021YFC22024022019JH2/10100009

2024

稀有金属材料与工程
中国有色金属学会,中国材料研究学会,西北有色金属研究院

稀有金属材料与工程

CSTPCD北大核心
影响因子:0.634
ISSN:1002-185X
年,卷(期):2024.53(3)
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