首页|煤油流量对NiCrBSi-CrSi2涂层微观结构及高温磨损性能的影响

煤油流量对NiCrBSi-CrSi2涂层微观结构及高温磨损性能的影响

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在12CrMoVG基体上通过超音速火焰喷涂(HVOF)技术,分别采用不同煤油流量制备了 NiCrBSi-CrSi2复合涂层.利用XRD、SEM、EDS、Raman、维氏显微硬度计、电子拉伸试验机和高温旋转式摩擦磨损试验机分别表征了不同煤油流量下涂层物相、组织结构、力学性能和高温摩擦磨损性能.结果表明:不同煤油流量涂层的物相组成基本相同,均有y-Ni、Ni3B、Cr2B、CrSi2和Cr5Si3,但随着煤油流量的升高,涂层中的CrSi2和Cr2B的部分会分别转变为Cr5Si3和CrB相.涂层显微硬度和结合强度随着煤油流量的升高均呈现先增后减的趋势,孔隙率和磨损率表现出先减后增的趋势.当煤油流量为30L/h时,粉末熔融效果最好,涂层的孔隙率最低为0.17%,显微硬度(HV0.3)最高达到5576.2 MPa,结合强度最高为59 MPa,磨损率最低为2.84×10-14m3·(N·m)-1.磨痕表面产生的Cr2O3、SiO2和NiCr2O4等氧化物以及较高的涂层硬度使得30 L/h的涂层显示出最优的耐高温摩擦磨损性能.涂层的磨损机制以氧化磨损和黏着磨损为主.
Effect of Kerosene Flow on Microstructure and High Temperature Wear Properties of NiCrBSi-CrSi2 Coating
The NiCrBSi-CrSi2 composite coating was prepared by supersonic flame spraying(HVOF)technology on the 12CrMoVG substrate at different kerosene flow rates.The coating phase,microstructure,mechanical properties and high temperature friction and wear properties were characterized by XRD,SEM,EDS,Raman,Vickers microhardness tester,electronic tensile testing machine and high temperature rotational friction and wear testing machine at different kerosene flow rates.The results show that the phase composition of coatings is basically the same,all of which have y-Ni,Ni3B,Cr2B,CrSi2 and Cr5Si3.But as the kerosene flow increases,the CrSi2 and Cr2B parts in the coating will be transformed into Cr5Si3 and CrB phases,respectively.The microhardness and bonding strength of the coating show a trend of first increasing and then decreasing with the increase in kerosene flow,and the porosity and wear rate show a trend of first decreasing and then increasing.When the kerosene flow rate is 30 L/h,the powder melting effect is the best,the porosity of the coating is the lowest of 0.17%,the microhardness(HV0.3)is the highest of 5576.2 MPa,the bonding strength is the highest of 59 MPa,and the wear rate is the lowest of 2.84×10-14 m3·(N·m)-1.Oxides such as Cr2O3,SiO2 and NiCr2O4 generated on the surface of the wear mark and the high coating hardness make the coating at the kerosene flow rate of 30 L/h show optimal high temperature friction and wear resistance.The wear mechanism of the coating is mainly oxidative wear and adhesive wear.

supersonic sprayingNiCrBSi-CrSi2 composite coatingkerosene flowmicrostructurehigh temperature wear performance

王志强、刘侠、张世宏、任奕、杨康、杨阳、薛召露

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安徽工业大学先进金属材料绿色制备与表面技术教育部重点实验室,安徽马鞍山 243002

安徽工业大学材料科学与工程学院,安徽马鞍山 243002

超音速喷涂 NiCrBSi-CrSi2复合涂层 煤油流量 显微组织 高温磨损性能

国家自然科学基金国家自然科学基金安徽省高等学校协同创新项目

52201058U22A20110GXXT-2020-071

2024

稀有金属材料与工程
中国有色金属学会,中国材料研究学会,西北有色金属研究院

稀有金属材料与工程

CSTPCD北大核心
影响因子:0.634
ISSN:1002-185X
年,卷(期):2024.53(3)
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