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铁电材料湿敏性能的研究进展

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对湿度的精密监测关系着一些潮解材料的保存,电子仪器的测量精准度等各个方面.高性能湿度传感器在现代工业、农业、医疗等领域均具有广泛的用途.湿度敏感材料包括介电材料、半导体材料、金属材料等.作为一种特殊的含有自发电极化的介电材料,铁电材料在湿敏传感器领域的应用越来越受到人们的关注.理论上,铁电材料的电极化对于表面的极性水分子具有强的吸附作用,同时,表面附着的极性水分子也可以反过来影响铁电材料的铁电极化、介电、电阻抗等性能.因此,铁电材料在高性能湿敏传感器件中具有重要的应用前景,铁电湿敏材料具有灵敏度高、响应快、稳定性好等优点.本文综述了铁电湿敏材料的发展历史和现状,详细总结了铁电材料湿度传感的物理机制.将铁电湿敏材料按类别、性质分为铁电纳米、铁电陶瓷、铁电薄膜、铁电单晶四大部分,分别综述了它们湿敏特性的研究进展及影响湿敏性能的各种因素,以期为未来新型铁电材料的湿敏研究提供一些科学参考.
Research Progress of the Humidity-Sensitive Properties of Ferroelectric Materials
The precise monitoring of humidity is related to the preservation of some deliquescent materials,the measurement accuracy of electronic instruments and other aspects.High-performance humidity sensors have a wide range of uses in modern industry,agriculture,and medicine.Humidity sensitive materials include dielectric materials,semiconductor materials,metal materials,etc.Ferroelectric materials are a special kind of dielectric material containing spontaneous electrodes,and their application in the field of humidity-sensitive sensors is receiving increasing attention.Theoretically,the electrodeposition of ferroelectric materials has a strong adsorption effect on the polar water molecules on the surface,and at the same time,the polar water molecules attached to the surface can in turn affect the ferroelectric polarization,dielectric and electrical impedance properties of ferroelectric materials.Therefore,ferroelectric materials have important application prospects in high-performance wet-sensitive sensor devices,and ferroelectric wet-sensitive materials have the advantages of high sensitivity,fast response,and good stability.This paper reviewed the development history and status of ferroelectric moisture-sensitive materials,and summarized the physical mechanism of humidity sensing by ferroelectric materials.The ferroelectric moisture-sensitive materials were classified into four major parts,namely,ferroelectric nano,ferroelectric ceramic,ferroelectric thin film,and ferroelectric single crystal,according to their categories and properties,and the research progress of their moisture-sensitive properties and various factors affecting the moisture-sensitive performance were reviewed,in order to provide some scientific references for the future research of moisture-sensitive of new ferroelectric materials.

humidity sensorhumidity sensitive materialsferroelectric effectferroelectric materialsprogress

贾艳敏、郭迪

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西安邮电大学理学院,陕西西安 710121

西安邮电大学通信与信息工程学院,陕西西安 710121

湿度传感器 湿敏材料 铁电效应 铁电材料 进展

国家自然科学基金

22179108

2024

稀有金属材料与工程
中国有色金属学会,中国材料研究学会,西北有色金属研究院

稀有金属材料与工程

CSTPCD北大核心
影响因子:0.634
ISSN:1002-185X
年,卷(期):2024.53(4)
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