首页|放电等离子烧结WMoNbTaV-Al2O3高熵合金组织及磨损性能

放电等离子烧结WMoNbTaV-Al2O3高熵合金组织及磨损性能

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以金属粉末为原料,采用放电等离子烧结技术制备新型含α-Al2O3的WMoNbTaV难熔高熵合金,研究了烧结温度对合金致密化行为、相结构、显微组织和耐磨性能的影响.结果表明:在1800~1900 ℃烧结时,WMoNbTaV-Al2O3高熵合金基体具有单一 bcc相结构,Al2O3的平均晶粒尺寸为1.15 μm.随着烧结温度升高,合金的晶粒尺寸增大,致密度和显微硬度也在不断增高,在1900 ℃烧结时硬度达到7967.4 MPa.1900 ℃烧结得到的合金具有优异的耐磨性,磨损量仅为1800 ℃烧结合金的一半.且WMoNbTaV-Al2O3高熵合金的耐磨性远高于纯W材料.当磨料粒度为37.5 μm时,1900 ℃烧结的合金磨损量为0.9 mg,磨损性能是纯W材料的83倍.
Microstructure and Wear Properties of WMoNbTaV-Al2O3 High Entropy Alloy Prepared by Spark Plasma Sintering
A new refractory high entropy alloy WMoNbTaV containing Al2O3 was prepared by spark plasma sintering.The effects of sintering temperature on densification behavior,phase structure,microstructure and wear resistance of the alloy were studied.The results show that when sintered at 1800-1900 ℃,the matrix of WMoNbTaV-Al2O3 has a single bcc phase structure,and the average grain size of Al2O3 is 1.15 μm.With the increase in sintering temperature,the grain size of the alloy increases,the density and microhardness also increase,and the hardness reaches 7967.4 MPa when the sintering temperature is 1900 ℃.The alloy sintered at 1900 ℃ has excellent wear resistance,and the wear amount is only half of that of the alloy sintered at 1800 ℃.The wear resistance of WMoNbTaV-Al2O3 high entropy alloy is much higher than that of pure W material.When the abrasive particle size is 37.5 μm,the wear mass loss of alloy sintered at 1900 ℃ is 0.9 mg,and the wear resistance of alloy is 83 times higher than that of pure W material.

spark plasma sinteringrefractory high entropy alloymicrostructurewear

刘美君、徐流杰、李洲、郭明宜、胡继康、申华海

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河南科技大学材料科学与工程学院,河南洛阳 471000

河南科技大学河南省高温难熔金属材料国际联合实验室,河南洛阳 471000

中国工程物理研究院核物理与化学研究所,四川绵阳 621900

放电等离子烧结 难熔高熵合金 显微组织 磨损性能

国家自然科学基金国家重点研发计划

U20041802020YFB2008400

2024

稀有金属材料与工程
中国有色金属学会,中国材料研究学会,西北有色金属研究院

稀有金属材料与工程

CSTPCD北大核心
影响因子:0.634
ISSN:1002-185X
年,卷(期):2024.53(5)
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