首页|Zr-1.0Ti-0.35Nb合金热变形行为研究

Zr-1.0Ti-0.35Nb合金热变形行为研究

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乏燃料后处理强酸、强氧化性、强放射性的工作环境,对后处理溶解器选材、加工工艺提出了严苛要求.本工作研究了自主设计Zr-1.0Ti-0.35Nb合金在670~750 ℃温度范围、3种不同应变速率0.01、0.1和1 s-1条件下的热压缩变形行为,分析了热压缩过程中该合金的微观组织特征,并基于峰值应力构建了其热变形本构模型.结果表明,应变速率和变形温度对Zr-1.0Ti-0.35Nb合金热变形过程具有显著影响,流变应力随应变速率增加而增大,随变形温度的升高而减小,达到峰值应力后流变曲线呈现明显动态再结晶特征;提高变形温度有助于发生动态再结晶和晶粒长大;基于Arrhenius本构方程计算得到Zr-1.0Ti-0.35Nb合金的热变形激活能为225.8 kJ/mol,硬化指数为5.62,说明合金元素Ti使锆合金的热变形激活能升高;实验值与预测值之间的相关系数为0.97427,平均相对误差为6.15%,证实此本构方程预测Zr-1.0Ti-0.35Nb合金流变应力的准确性,能够为新型锆合金热加工工艺优化提供理论指导.
Investigations on Hot Deformation Behavior of Zr-1.0Ti-0.35Nb Alloy
The harsh environment with strong acid,high oxidability and irradiation raises urgent demand for advanced structural materials used for reprocessing dissolver of spent nuclear fuels.In this paper,hot compression behavior of a Zr-1.0Ti-0.35Nb alloy was investigated at the strain rate of 0.01,0.1,1 s-1 and in the temperature range of 670-750 ℃.Microstructural evolution during the hot compression was analyzed.The results reveal that the strain rate and deformation temperature both significantly affect the hot deformation behavior of Zr-1.0Ti-0.35Nb alloy.Flow stress increases with the accelerated strain rate and decreases with the elevated temperature.Beyond peak stress,the flow curve exhibits apparent dynamic recrystallization characteristics.Elevated deformation temperature favors dynamic recrystallization and grain growth.An Arrhenius-type constitutive model was established based on the obtained peak stress values,in which the activation energy is calculated as 225.8 kJ/mol,suggesting a Ti-induced elevation of activation energy and the hardening index is 5.62.A correlation coefficient of 0.97427 and average relative error of 6.15%are obtained between the experimental and predicted values,demonstrating sound applicability of the constitutive model that is expected to guide processing optimization for the new Zr-1.0Ti-0.35Nb alloy.

spent nuclear fuel reprocessingZr-1.0Ti-0.35Nb alloyhot deformationdynamic recrystallizationconstitutive model

公维佳、陈吉昌、张敬翊、陈兆奎、李中奎、李金山

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西北工业大学材料学院,陕西西安 710072

西北工业大学太仓长三角研究院清洁能源研究中心,江苏太仓 215400

中机第一设计研究院有限公司,安徽合肥 230601

西北工业大学伦敦玛丽女王大学工程学院,陕西西安 710072

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乏燃料后处理 Zr-1.0Ti-0.35Nb合金 热变形 动态再结晶 本构模型

国家自然科学基金国家自然科学基金国家自然科学基金国防科技工业局乏燃料后处理科研专项

12005170U2067217U2230124

2024

稀有金属材料与工程
中国有色金属学会,中国材料研究学会,西北有色金属研究院

稀有金属材料与工程

CSTPCD北大核心
影响因子:0.634
ISSN:1002-185X
年,卷(期):2024.53(6)
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