首页|预变形Mo-0.3La合金的热变形行为研究

预变形Mo-0.3La合金的热变形行为研究

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采用Gleeble-3500热模拟机在变形温度为973~1273 K、应变速率为0.001~0.1s-1、真应变为60%的实验条件下,对预变形Mo-0.3La合金的热变形行为进行了研究,并采用包含Zene-Hollomon参数的双曲正弦模型,建立了热变形流变方程.结果表明:预变形Mo-0.3La合金的真应力-应变曲线具有动态再结晶特征,在较低的温度(973 K)/较高的应变速率(0.1 s-1)下,表现出加工硬化,在1273 K低应变速率(0.001和0.005 s-1)下动态再结晶具有显著性;合金含有31.65%大角度晶界,再变形后大角度晶界减少至17.14%,且存在少量的再结晶晶粒(6.08%);变形温度升高,大角度晶界和再结晶晶粒增多;由流变方程得到平均变形激活能Q为287.08 kJ/mol,应力指数n为14.40,依据流变方程计算出的应力理论值与实际值的平均相对误差仅3.25%.
Hot Deformation Behavior of Pre-deformed Mo-0.3La Alloy
The hot deformation behavior of pre-deformed Mo-0.3La alloy was studied on the Gleeble-3500 thermal-mechanical simulator at 973-1273 K with the deformation rate of 0.001-0.1 s-1 and the true strain of 60%,and the constitutive equation was established by hyperbolic sine model with Zene-Hollomon parameter.The results show that the dynamic recrystallization characteristics of the true stress-true strain curves are observed.Pre-deformed Mo-0.3La alloy exhibits work hardening at high strain rate of 0.1 s-1 or low temperature of 973 K,and dynamic recrystallization is significant at low strain rate of 0.001 and 0.005 s-1 at 1273 K.The high angle grain boundary of the pre-deformed alloy is 31.65%.After redeformation,the high grain boundary fraction decreases to 17.14%with few recrystallized grains(6.08%).With the increase in deformation temperature,the fraction of high angle grain boundaries and recrystallized grains increases.Calculated by the constitutive equation,the deformation activation energy Q is 287.08 kJ/mol,and the stress exponent n is 14.40.The average relative error between the theoretical stress calculated by the constitutive equation and experimental results is only 3.25%.

pre-deformedMo-0.3La alloyhot deformationmicrostructure

张晓、任宝江、冯鹏发、安耿、卜春阳、胡平、席莎、李晶、周莎、王快社

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西安建筑科技大学冶金工程学院,陕西西安 710055

金堆城钼业股份有限公司,陕西西安 710077

陕西省"四主体一联合"先进钼化合物功能材料校企联合研究中心,陕西西安 710077

西安建筑科技大学功能材料加工国家与地方联合工程研究中心,陕西西安 710055

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预变形 Mo-0.3La合金 热变形 微观组织

2024

稀有金属材料与工程
中国有色金属学会,中国材料研究学会,西北有色金属研究院

稀有金属材料与工程

CSTPCD北大核心
影响因子:0.634
ISSN:1002-185X
年,卷(期):2024.53(12)