首页|退火温度对(AlCoCrFeNi)1-x/(CoCrNi)x复合材料耐磨和耐腐蚀性的影响

退火温度对(AlCoCrFeNi)1-x/(CoCrNi)x复合材料耐磨和耐腐蚀性的影响

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利用选区激光融化(SLM)技术制备了耐磨耐腐蚀性能优异的(AlCoCrFeNi)1-x/(CoCrNi)x(x=20%,质量分数)复合材料.并对其进行了退火处理.利用XRD、SEM、EDS、EBSD、硬度计、摩擦磨损试验机、电化学工作站和X射线光电子能谱分析等技术手段研究了不同退火温度(600、800、1000 ℃)对(AlCoCrFeNi)1-x/(CoCrNi)x(x=20%,质量分数)的组织结构、硬度、耐磨性和耐腐蚀性的影响规律及机制.经过600 ℃退火后,复合材料的相组成没有变化,均由bcc相和B2相组成,晶粒比退火前更加均匀细小.经过800和1000 ℃退火后,fcc相出现,晶粒更加粗大.退火温度越高,fcc相比重越大,晶粒尺寸越大.随退火温度的升高,复合材料的硬度和耐磨性先提高后降低.由于细晶强化作用,600 ℃退火试样的硬度最高和耐磨性最好,与退火前的试样相比,硬度提高了 26.9%,磨损失重降低了 32%.退火处理促进了钝化膜中Cr2O3的富集,提高了复合材料的耐腐蚀性,1000 ℃退火试样的耐腐蚀性最优.
Effect of Annealing Temperature on Wear Resistance and Corrosion Resistance of(AlCoCrFeNi)1-x/(CoCrNi)x Composites
(AlCoCrFeNi)1-x/(CoCrNi)x(x=20%,mass fraction)composites with excellent wear and corrosion resistance were prepared by selective laser melting(SLM).Then the composites were annealed at different temperatures(600,800,1000 ℃).The effects of annealing temperature on the microstructure,hardness,wear resistance and corrosion resistance of the composites were studied by XRD,SEM,EDS,EBSD,hardness tester,friction and wear tester,electrochemical workstation and X-ray photoelectron spectroscopy.After annealing at 600 ℃,the phase composition of the composites does not change,which is composed of bcc phase and B2 phase,and the grains are more uniform and finer than those before annealing.After annealing at 800 and 1000 ℃,the fcc phase appears and the grains are coarser.The higher the annealing temperature,the heavier the fcc and the larger the grain size.With the increase in annealing temperature,the hardness and wear resistance of the composites increase first and then decrease.Due to the fine grain strengthening effect,the hardness and wear resistance of the sample annealed at 600 ℃ are the highest.Compared with the sample before annealing,the hardness of the annealed sample is increased by 26.9%and the wear mass loss is decreased by 32%.Annealing treatment promotes the enrichment of Cr2O3 in the passive film and improves the corrosion resistance of the composites.The sample at 1000 ℃ shows the best corrosion resistance.

compositesselective laser melting moldingannealing treatmentwear resistancecorrosion resistance

郭晶、王德兴、郑杜彬、翟若凯、马陈、李玉道

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山东农业大学机械与电子工程学院,山东泰安 271018

山东农业大学 山东省园艺机械与装备重点实验室,山东泰安 271018

复合材料 选区激光熔化成型 退火处理 耐磨性 耐腐蚀性

2024

稀有金属材料与工程
中国有色金属学会,中国材料研究学会,西北有色金属研究院

稀有金属材料与工程

CSTPCD北大核心
影响因子:0.634
ISSN:1002-185X
年,卷(期):2024.53(12)