首页|添加剂对钨铜合金组织及性能的影响

添加剂对钨铜合金组织及性能的影响

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以铜粉、钨粉为原料,采用机械合金化、放电等离子烧结(SPS)方法制备W-Cu合金,采用SEM、XRD、维氏硬度计、电子密度仪、电导率测试仪等分析了不同烧结温度、添加剂Y2O3和Cr添加量对W-Cu合金显微组织和物理力学性能的影响.实验结果表明:随着烧结温度的升高,W、Cu两相分布越来越均匀,合金的致密度、硬度以及电导率均有所增大,烧结温度为1 100 ℃时所制备的W-Cu合金综合物理力学性能最佳.随着Y2O3含量的增多,W-Cu合金晶粒变细,硬度升高,致密度和电导率下降.随着Cr含量的增多,W-Cu合金电导率下降,但硬度与致密度先略有增加再大幅下降,W-Cu-0.5Cr的综合物理力学性能最好.因此,添加少量添加剂可有效改善SPS产品(W-Cu合金)的组织结构及物理力学性能.
Effect of Additives on Microstructure and Properties of W-Cu Alloys
Using copper powder and tungsten powder as raw materials,W-Cu alloys were prepared by me-chanical alloying and spark plasma sintering.The effects of different sintering temperatures and the addi-tions of Y2O3 and Cr additives on the microstructure and physical and mechanical properties of the alloys were analyzed using SEM,XRD,Vickers hardness tester,electron densitometer,and conductivity tester.The experimental results show that as the sintering temperature increases,the distribution of W and Cu phases becomes more uniform,and the density,hardness,and conductivity of the alloys increase.The W-Cu alloy prepared at a sintering temperature of 1 100℃ exhibits the best comprehensive physical and mechani-cal properties.With the increase in Y2O3 content,the grains of the W-Cu alloys become finer,the hardness increases,while the density and conductivity decrease.In addition,with the increase in Cr content,the con-ductivity of the W-Cu alloys decreases,but the hardness and density increase slightly and then decrease sig-nificantly.The W-Cu-0.5Cr alloy possesses the best comprehensive physical and mechanical properties.Therefore,adding a small amount of additives can effectively improve the microstructure and physical and mechanical properties of the SPS products(W-Cu alloys).

W-Cu alloyspark plasma sinteringsintering temperatureadditiveY2O3Crmicrostructurephysical and mechanical property

李滨、郭圣达、李宇涛、张建波、刘柏雄、刘瑾萱、唐发辉、杨博

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江西理工大学材料科学与工程学院,江西赣州 341000

江西耀升钨业股份有限公司,江西赣州 341300

江西宝航新材料有限公司,江西南昌 330000

江西先进铜产业研究院,江西赣州 341000

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W-Cu合金 放电等离子烧结 烧结温度 添加剂 Y2O3 Cr 显微组织 物理力学性能

2024

稀有金属与硬质合金
中国有色金属学会,长沙有色冶金设计研究院有限公司

稀有金属与硬质合金

北大核心
影响因子:0.32
ISSN:1004-0536
年,卷(期):2024.52(4)