稀有金属与硬质合金2024,Vol.52Issue(4) :59-63,77.DOI:10.19990/j.issn.1004-0536.2024.04.059.05

掺杂Al2O3对LiNbO3压电陶瓷组织和性能的影响研究

Study on Effect of Al2O3 Doping on Microstructure and Properties of LiNbO3 Piezoelectric Ceramics

朱飞 禹建功 王一强 周红梅
稀有金属与硬质合金2024,Vol.52Issue(4) :59-63,77.DOI:10.19990/j.issn.1004-0536.2024.04.059.05

掺杂Al2O3对LiNbO3压电陶瓷组织和性能的影响研究

Study on Effect of Al2O3 Doping on Microstructure and Properties of LiNbO3 Piezoelectric Ceramics

朱飞 1禹建功 1王一强 1周红梅1
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作者信息

  • 1. 河南理工大学机械与动力工程学院,河南焦作 454000
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摘要

通过真空热压烧结法在900 ℃、35 MPa下保温120 min制备铌酸锂(LiNbO3,简称LN)压电陶瓷,研究掺杂不同含量的Al2O3对其压电性能的影响.通过物相、密度、微观组织、压电性能和介电性能分析发现,在0.5%~3%(摩尔分数)Al2O3掺杂量范围内,所有LN压电陶瓷样品的主体衍射峰位置相同、峰形尖锐,均为类钙钛矿结构;随着Al2O3掺杂量的增加,LN压电陶瓷晶粒尺寸逐渐减小,气孔增大、增多,密度和压电常数d33均呈先增大后减小的趋势,均在Al2O3掺杂量为1%时达到最大,分别为4.65 g/cm3和11.3 PC/N,此压电常数相较于激光烧结法制备的LN压电陶瓷提高了 88.3%.在1 MHz测试频率下,LN压电陶瓷的相对介电常数随着Al2O3掺杂量的增加而逐渐增大.

Abstract

Lithium niobate(LiNbO3,LN)piezoelectric ceramics were prepared by vacuum hot-pressing sin-tering at 900 C and 35 MPa for 120 min.The effects of different Al2O3 doping amounts on their piezoelec-tric properties were studied.Through the analysis of phase,density,microstructure,piezoelectric and dielec-tric properties,it is found that within the range of Al2O3 doping amounts of 0.5%~3%(molar fraction),all LN piezoelectric ceramics samples exhibit the same position of main diffraction peaks that are sharp and indicative of a perovskite-type structure.with the increase of Al2O3 doping amount,the particle size of LN piezoelectric ceramics gradually decreases while the porosity increases both in size and quantity.In addi-tion,the density and piezoelectric constant d33 increase at first and then decrease,reaching their maximum of 4.65 g/cm3 and 11.3 pC/N,respectively,at an Al2O3 doping amount of 1%.The above piezoelectric con-stant is 88.3%higher than that of LN piezoelectric ceramics prepared by laser sintering.At the test fre-quency of 1 MHz,the relative dielectric constant of LN piezoelectric ceramics increases gradually with the increase of Al2O3 doping amount.

关键词

压电陶瓷/铌酸锂/真空热压烧结/Al2O3掺杂量/压电常数/介电常数/微观组织

Key words

piezoelectric ceramics/lithium niobate/vacuum hot-pressing sintering/Al2O3 doping amount/pie-zoelectric constant/dielectric constant/microstructure

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出版年

2024
稀有金属与硬质合金
中国有色金属学会,长沙有色冶金设计研究院有限公司

稀有金属与硬质合金

CSCD北大核心
影响因子:0.32
ISSN:1004-0536
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