首页|铝工业危废铝灰的高效处置新技术

铝工业危废铝灰的高效处置新技术

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针对当前铝工业中危废铝灰处置所面临的能耗高、效率低等突出问题,通过工艺和技术创新,在热力学分析的基础上提出采用磨细、微波场、惰性大颗粒辅助强化等新型处置技术,分别以氯气、氯化硅、氯气-氯化硅为氯化剂,研发了5 条铝灰高效氯化加工新工艺(以氯气为氯化剂的铝灰高效利用方法,以氯气为氯化剂的二次铝灰高值化利用方法,以氯气为氯化剂的铝灰高效制备氮化铝方法,以氯化硅为氯化剂的铝灰高效制备氟化铝方法,以氯气-氯化硅为氯化剂的铝灰制备氟化铝方法).这5 种工艺可有效提升了铝灰的资源利用率、处置效率,实现铝灰深度高值化利用(制备氮化铝、氟化铝),具有显著的经济效益和社会效益.
New Technology of Efficient Disposal of Aluminum Ash in Aluminum Industry
Aiming at the prominent problems of high energy consumption and low efficiency in the dispos-al of hazardous waste aluminum ash in the aluminum industry,through process and technological innova-tion,based on thermodynamic analysis,new disposal technologies such as grinding,microwave field and inert large particle assisted strengthening were proposed.Chlorine,silicon chloride and chlorine-silicon chloride were used as chlorinating agents,respectively.Five new processes for efficient chlorination of a-luminum ash were developed(a method for efficient utilization of aluminum ash with chlorine as chlori-nating agent,a method for high-value utilization of secondary aluminum ash with chlorine as chlorinating agent,a method for efficient preparation of aluminum nitride with aluminum ash with chlorine as chlorina-ting agent,a method for efficient preparation of aluminum fluoride with aluminum ash with silicon chlo-ride as chlorinating agent,a method for preparation of aluminum fluoride with aluminum ash with chlo-rine-silicon chloride as chlorinating agent).These five processes can effectively improve the resource uti-lization rate and disposal efficiency of aluminum ash,and realize the deep high-value utilization of alumi-num ash(preparation of aluminum nitride and aluminum fluoride),which has significant economic and social benefits.

harmless treatment of aluminum ashresource utilizationchlorinationchlorine gassilicon chlorideefficient disposalaluminum nitridealuminium fluoride

余剑、闫飞飞、潘锋、杜占

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中铝环保节能集团有限公司,河北 雄安 071700

中国科学院过程工程研究所,北京 100089

铝灰资源化 铝灰无害化 氯化 氯气 氯化硅 高效处置 氮化铝 氟化铝

2024

有色冶金节能
中国有色工程有限公司

有色冶金节能

影响因子:0.261
ISSN:1008-5122
年,卷(期):2024.40(5)