Z型全氟聚醚的合成及应用研究进展
Progress in Synthesis and Application of Z-type Perfluoropolyethers
张文 1刘波 1张鸣 1杨旭仓 1钟志刚1
作者信息
- 1. 中昊晨光化工研究院有限公司,有机氟材料四川省重点实验室,四川自贡 643201
- 折叠
摘要
对四氟乙烯光氧化反应、过氧基团的去除和端基处理合成Z型全氟聚醚的过程进行了系统论述,并深入分析了光氧化反应机理.按照Z型全氟聚醚端基类型的差异,分别介绍了带惰性端基和功能性端基Z型全氟聚醚的应用进展,分析了现有合成工艺存在的问题及解决方法,以期为Z型全氟聚醚的合成及应用研究提供有益参考.
Abstract
The synthesis processes of Z-type perfluoropolyethers,such as photooxidation reaction of tetrafluo-roethylene,removal of peroxy groups and end-group treatment were systematically discussed,and the reaction mechanism of photooxidation was deeply analyzed.According to the differences in the end group types of Z-type perfluoropolyethers,the application progress of Z-type perfluoropolyethers with inert and functional end groups was introduced,and synthetic conundrums of Z-type perfluoropolyethers were analyzed,with a view to providing useful references for the synthesis and application research of Z-type perfluoropolyethers.
关键词
Z型全氟聚醚/光氧化反应/过氧化物/端基氟化Key words
Z-type perfluoropolyethers/photooxidation reaction/peroxide/fluorination of end groups引用本文复制引用
出版年
2024
NETL
NSTL
万方数据