芳乙酰叠氮的制备及其在有机合成中的应用进展
Preparation of Phenacyl Azides and Their Application Advances in Organic Synthesis
佘春艳 1王安静 1刘珊 1舒文明 1余维初1
作者信息
- 1. 长江大学化学与环境工程学院 油气田清洁生产与污染物控制工程研究中心 湖北荆州 434023
- 折叠
摘要
作为一种非常重要的有机叠氮化合物,芳乙酰叠氮是有机合成中优良的合成子,可广泛用于构建各种含氮化合物.它的合成方法简单,反应活性高,反应位点多,不仅可以在一个位点上发生反应,还可以同时在两个或多个位点上发生反应,从而使其反应类型相当丰富.基于近年来芳乙酰叠氮在有机合成中取得了诸多进展,主要综述了芳乙酰叠氮的各种制备方法以及按照具体的反应类型分类的研究结果,并对代表性的例子及其反应机理进行了讨论和分析.
Abstract
Phenacyl azides,a kind of crucial organic azide,serve as a valuable synthetic substrate in organic synthesis.They have extensive applications in constructing diverse nitrogen-containing compounds.Their straightforward synthetic methods,elevated reactivity and multiple reaction sites enable them to undergo reactions at a single site or simultaneously at multiple sites,resulting in a wide range of reaction types.Based on the significant progress made in organic synthesis in recent years,various preparation methods of phenacyl azides and research results classified according to specific reaction types are mainly reviewed.Representative examples and reaction mechanisms are discussed and analyzed.
关键词
芳乙酰叠氮/制备/反应类型/应用进展Key words
phenacyl azide/preparation/types of reaction/application advance引用本文复制引用
出版年
2024
NETL
NSTL
万方数据