氧化型光电催化促进的C—H键官能团化反应研究进展
Recent Advances on C—H Functionalization via Oxidative Electrophotocatalysis
Hasil Aman 1常瑞 1叶俊涛1
作者信息
- 1. 上海交通大学化学化工学院 上海市手性药物分子工程重点实验室 上海 200240
- 折叠
摘要
惰性C—H键直接选择性官能团化反应是有机合成领域长久以来的挑战之一.虽然已经发展了多种策略,但仍亟待发展无需添加过渡金属和氧化剂的新方法.近年来,光电催化作为一种新兴策略,能够在温和条件下实现包括直接C—H键官能团化在内的多种挑战性转化反应,表现出强大的潜力.从机理的角度出发,总结了通过阳极氧化的光电催化策略实现C—H键官能团化反应的最新研究进展,并简单讨论了这个新兴领域所面临的挑战和机遇.
Abstract
Direct and selective functionalization of relatively inert C—H bonds is a long-standing challenge in synthetic chemistry.While many strategies have been developed to date,new approach that does not require the use of transition-metals and oxidants is in high demand.Recently,electrophotocatalysis has emerged as a powerful means to effect direct C—H func-tionalization and other types of challenging transformations under mild reaction conditions.The recent advances on electro-photocatalytic C—H functionalization via anode oxidation are highlighted with a focus on mechanistic aspects.Challenges and opportunities of this emerging field are also discussed.
关键词
光电催化/电化学/C—H键官能团化/氧化反应Key words
electrophotocatalysis/electrochemistry/C—H functionalization/oxidation引用本文复制引用
基金项目
国家自然科学基金(22371180)
国家自然科学基金(22001163)
出版年
2024
NETL
NSTL
万方数据