Progress in Transition-Metal-Catalyzed Carbonylative Cycloadditions Using Carbon Monoxide
Transition-metal-catalyzed cycloadditions have been evolved as important and efficient methods to construct cyclic molecules.Among them,transition-metal-catalyzed cycloadditions using carbon monoxide(CO)gas as the 1C synthon provide their unique and powerful approaches to build various cyclic molecules within a carbonyl group,which either acts as an important functional group within the cycloadducts,or can be further elaborated to other functional groups.The tremendous advances in this field are introduced.
cyclic moleculecarbon monoxide(CO)gastransition metal catalysiscarbonylationcycloaddition