过渡金属催化C—S键活化与转化研究进展
Recent Advances in Transition-Metal-Catalyzed C—S Bond Activation and Transformations
郭凯杰 1符昕姝 1李靖 1陈艳 1胡美丽 1堵锡华 1谢屿阳 2何燕1
作者信息
- 1. 徐州工程学院材料与化学工程学院 江苏徐州 221018
- 2. 徐州医科大学江苏省新药研究与临床药学重点实验室 江苏徐州 221004
- 折叠
摘要
C—S键的活化,对于药物分子、高性能聚合物和复合材料的制备以及生物医学、环境保护等领域具有重要作用,过渡金属催化C—S键的活化与转化更是具有广泛的应用前景.根据有机硫化物中碳原子的杂化类型进行分类,综述了近十年来过渡金属催化C(sp)/C(sp2)/C(sp3)—S键活化与转化的研究进展,采用不同的过渡金属催化剂,着重讨论了底物适用性和反应机理,并对该领域存在的挑战以及未来发展趋势进行了讨论和展望.
Abstract
The activation of C—S bond plays a crucial role in the preparation of drug molecules,high-performance polymers and composite materials,as well as in biomedical,environmental protection and other fields.Transition-metal-catalyzed C—S bond activation and transformations have a wide range of application prospects.Herein,the recent advances in transi-tion-metal-catalyzed C(sp)/C(sp2)/C(sp3)—S bond activation and transformations are summarized according to the hybridiza-tion types of carbon atoms in organosulfur compounds.Various transition metal catalysts are utilized.The substrate applicabil-ity and reaction mechanisms are emphatically discussed.Finally,the challenges and future development trends of this research field are discussed and prospected.
关键词
C—S键活化/过渡金属催化/有机硫化物Key words
C—S bond activation/transition metal catalysis/organosulfur compounds引用本文复制引用
基金项目
徐州市科技计划(KC21286)
徐州工程学院"大创计划"(2022)(xcx2022013)
出版年
2024
NETL
NSTL
万方数据