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酸级萤石粉的选矿制备工艺试验研究

Experimental research on beneficiation preparation process of acid grade fluorite powder

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萤石作为不可或缺的战略储备矿产资源,对我国氟化工发展起支撑作用.伴随着酸级萤石(CaF2质量分数不小于97%)需求量和消耗量不断增大以及高品位优质萤石资源逐渐匮乏,高效开发利用萤石资源制备高纯度酸级萤石工艺研究具有重要意义.本文以某低品位萤石矿为对象,开展酸级萤石粉选矿制备工艺试验研究,探究磨矿细度、捕收剂、抑制剂、调整剂及浮选流程等条件对选矿制备酸级萤石粉的影响,并通过先进科学的选矿工艺获得高纯度酸级萤石产品.结果表明:萤石矿预先浮选脱除硫化矿,选出的硫化矿经1次粗选分离可得到铅锌精矿;脱硫尾矿经"1粗3扫-粗精矿再磨-8次精选"工艺流程回收萤石,最终得到CaF2质量分数为97.70%,萤石回收率为92.21%的萤石精矿,提高了萤石精矿产品附加值.本文成果为该类资源的整体高效利用提供了技术依据.
Fluorite,as an indispensable strategic reserve mineral resource,plays a supporting role in the development of fluorine chemical industry in China. With the increasing demand and consumption of acid-grade fluorite (CaF2 mass fraction not less than 97%) and the gradual scarcity of high-grade and high-quality fluorite resources,it is of great significance to study the process of efficiently developing and utilizing fluorite resources to prepare high-purity acid-grade fluorite. In this paper,a low-grade fluorite mine is taken as the object to carry out an experimental study on the beneficiation and preparation process of acid fluorite powder,the effects of grinding fineness,collector,inhibitor,regulator and flotation process on the beneficiation preparation of acid fluorite powder is explored,and high-purity acid fluorite products are obtained through advanced scientific beneficiation technology. The results show that sulfide ore is removed by fluorite ore through pre-flotation,and the selected sulfide ore can be separated by one rough separation to obtain lead-zinc concentrate. The fluorite is recovered from the desulfurization tailings through the process of"1 coarse 3 sweeps-coarse concentrate re-grinding-8 times of selection",and the fluorite concentrate with CaF2 mass fraction of 97.70% and fluorite recovery rate of 92.21% are finally obtained,which improves the added value of fluorite concentrate products. The results provide a technical basis for the overall efficient utilization of such resources.

fluoritequartz typeflotationpre-desulfurizationcondition experiment

杨卓、张鹏羽、赵强、马钟琛、姜智

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中冶长天国际工程有限责任公司,湖南 长沙 410205

萤石 石英型 浮选 预先脱硫 条件试验

2025

工程建设
中冶长天国际工程有限责任公司(原长沙冶金设计研究院)

工程建设

ISSN:1673-8993
年,卷(期):2025.57(1)