冶金能源2024,Vol.43Issue(2) :60-64.

生物质炭对烟气脱硝脱汞的实验研究

Experimental study on denitrification and mercury removal of flue gas by bio-char

汪子棋 唐初阳 刘佳琦 宋金玲
冶金能源2024,Vol.43Issue(2) :60-64.

生物质炭对烟气脱硝脱汞的实验研究

Experimental study on denitrification and mercury removal of flue gas by bio-char

汪子棋 1唐初阳 1刘佳琦 1宋金玲1
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作者信息

  • 1. 辽宁科技大学土木工程学院
  • 折叠

摘要

文章从低成本角度对烧结烟气进行脱硝脱汞研究,选用木屑在低温慢速热解条件下(室温至600℃,5℃/min)制备生物质炭,然后利用硝酸对生物质炭进行改性,最后在固定床反应器上进行脱硝和脱汞实验.通过比表面积分析和傅里叶红外光谱分析,改性生物质炭具有更大的比表面积和微孔体积,其含氧官能团和碱性原子团明显增多,两者综合作用,使得改性生物质炭的脱硝脱汞能力明显优于生物质炭的.

Abstract

This study focused on the low-cost denitrification and demercuration from the sintering flue gas,sawdust was chosen to obtain bio-char under the slow low-temperature pyrolysis(from room temperature to 600℃ ,5℃ /min).Then,the bio-char was modified by the impregnation of ni-tric acid.At last,the modified bio-char finally was applied to carry out the experiments of denitrifica-tion and demercuration in a fixed-bed equipment.Compared with the bio-char,the modified bio-char made a better performance on the denitrification and demercuration of simulative flue gas.Moreo-ver,it was showed that modified bio-char has a lager specific surface area and microporous than that of bio-char by the analyses of Specific surface area(BET)and Infrared Fourier spectrum(FT-IR).The bio-char was modified to increase a number of oxygen-containing functional and alkaline atomic groups.The modified bio-char resulted to exhibit significance capacity on the removal of nitric oxide and mercury under the comprehensive effect of the two factors.

关键词

生物质炭/木屑/烧结烟气/脱硝/脱汞

Key words

bio-char/sawdust/sintering flue gas/denitration/demercuration

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基金项目

国家重点研发计划(2022YFE0208100)

辽宁省教育厅高等学校基本科研重点攻关项目(LJKZZ20220044)

辽宁科技大学研究生科技创新项目(LKDYC202228)

出版年

2024
冶金能源
中钢集团鞍山热能研究院有限公司

冶金能源

CSTPCD北大核心
影响因子:0.319
ISSN:1001-1617
参考文献量22
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