首页|臭氧—焙尘去除ZnSO4溶液中砷的响应曲面法优化研究

臭氧—焙尘去除ZnSO4溶液中砷的响应曲面法优化研究

Optimization of response surface methodology for removing arsenic from ZnSO4 solution by ozone roasting dust

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文章利用单因素试验,研究O3 流量、焙尘添加量和反应时间对砷去除率的影响.通过响应曲面RSM的Box-Beichen设计,以O3 流量、焙尘添加量和反应时间为影响因素,建立了砷去除率的预测模型.模型拟合结果表明:影响砷去除率的因素顺序依次是O3 流量>焙尘添加量>反应时间.砷去除率模型在99%的置信区间内显著,模型R2 为 0.997 8,说明该模型具有很好的拟合精度和可靠的预测力.模型优化的最优除砷条件为:O3 流量 867 mg/L,焙尘添加量16 g/L,反应时间46 min,在此条件下,预测砷去除率最大值为95.75%,试验值为95.03%,两者仅相差0.72 个百分点.综上,将RSM应用于砷去除率的工艺优化是一种有效的方法.
The article uses a single-factor experiment to study the effects of ozone flow rate,roasting dust addition amount,and reaction time on arsenic removal efficiency.By utilizing the Box-Behnken design of response surface methodology(RSM),with ozone flow rate,roasting dust addition amount,and reaction time as influencing factors,a predictive model for arsenic removal efficiency was estab-lished.The fitting results of the model indicate that the factors influencing arsenic removal efficiency are in the following order:ozone flow rate>roasting dust addition amount>reaction time.The arsenic removal model is significant within a 99%confidence interval,with an R-squared value of 0.997 8,demonstrating good fitting accuracy and reliable predictive power of the model.The optimized condi-tions for arsenic removal are determined to be an ozone flow rate of 867 mg/L,roasting dust addition a-mount of 16 g/L,and reaction time of 46 minutes.Under these conditions,the predicted maximum ar-senic removal rate is95.75%,with an experimental value of 95.03%,yielding a difference of only 0.72 percent point.In conclusion,the application of RSM for process optimization of arsenic removal rate is an effective method.

arsenic removalZnSO4solutionozoneroasting dustresponse surface methodology

刘殿传、张奇、夏洪应、张特、付光、陆占清

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云南驰宏锌锗股份有限公司

昆明理工大学冶金与能源工程学院

除砷 ZnSO4 溶液 臭氧 焙尘 响应曲面

国家重点研发计划云南省锌资源技术创新中心项目云南兴滇人才支撑项目产业创新人才项目(2019-1096)云南兴滇人才青年人才项目

2021YFC290281202405AK3400042018-73

2024

冶金能源
中钢集团鞍山热能研究院有限公司

冶金能源

CSTPCD北大核心
影响因子:0.319
ISSN:1001-1617
年,卷(期):2024.43(3)
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