首页|Mn2O3/AC微波处理烧结烟气协同脱硫脱硝研究

Mn2O3/AC微波处理烧结烟气协同脱硫脱硝研究

Study on synergistic desulfurization and denitrification of sintering flue gas by Mn2O3/AC microwave treatment

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利用浸渍法制备了孔隙结构丰富、Mn2O3负载良好的活性炭(Mn2O3/AC),通过微波脱硫脱硝实验探究了 Mn2O3/AC在不同温度、氧气含量和水含量条件下对烧结烟气微波脱硫脱硝的影响.实验结果表明,在180~420 ℃区间内,脱硫脱硝率随着温度的升高而增高,420 ℃时脱硫率为98.2%,脱硝率为80.25%,高温下Mn2O3/AC能够维持较高水平的脱硫性能;烧结烟气中的氧和水对脱硫脱硝有一定的促进作用,但含湿量过大对脱硫不利.Mn2O3/AC能够满足烧结烟气复杂成分微波脱硫脱硝要求,在O2和H2O(g)共存条件下脱硫脱硝率可维持在95%以上.Mn2O3/AC微波脱硫脱硝时不仅生成单质S和N2,还生成了硫酸盐与硝酸盐等副产物,进而降低了负载活性炭的性能.
Activated carbon(Mn2O3/AC)with rich pore structure and good Mn2O3 loading was pre-pared by impregnation method.The effects of Mn2O3/AC on micro wave desulfurization and denitrifica-tion of sintering flue gas at different temperatures,oxygen content and water content were investigated by microwave desulfurization and denitrification experiments.The experimental results show that the desulfurization and denitrification rate of Mn2O3/AC increases with the increase of temperature in the range of 180~420 ℃.The desulfurization rate is 98.2%and the denitrification rate is 80.25%at 420 ℃.Mn2O3/AC can maintain a high level of desulfurization performance at high temperature.The oxygen and water in the sintering flue gas have a certain promoting effect on the microwave desulfuriza-tion and denitrification,but the excessive moisture content is unfavorable to the desulfurization.Mn2O3/AC can meet the requirements of microwave desulfurization and denitrification of complex com-ponents in sintering flue gas,and the desulfurization and denitrification rate can be maintained above 95%under the coexistence of O2 and H2O(g).Mn2O3/AC microwave desulfurization and denitrifica-tion not only generated elemental S and N2,but also generated by-products such as sulfate and ni-trate,which reduced the performance of the loaded activated carbon.

microwaveimmersion methodMn2O3/ACsintering flue gasdesulfurization and denitrification

王健雄、石焱、胡长庆、孟令一、郝克

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华北理工大学冶金与能源学院,河北省现代冶金技术重点实验室

微波 浸渍法 Mn2O3/AC 烧结烟气 脱硫脱硝

国家自然科学基金河北省自然科学基金

52174312E2021209151

2024

冶金能源
中钢集团鞍山热能研究院有限公司

冶金能源

CSTPCD北大核心
影响因子:0.319
ISSN:1001-1617
年,卷(期):2024.43(4)