首页|近晶相液晶超结构的多元外场调控

近晶相液晶超结构的多元外场调控

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利用液晶的自组装和刺激响应特性,实现近晶相液晶多层级超结构的灵活构筑、动态操控和多功能应用对于激发更多前沿的创新性功能器件并推动液晶超结构的实用化进程具有重要意义.本文从近晶相液晶超结构的生长制备、多元外界刺激对缺陷结构的调制方法和动态调控规律等方面进行系统研究.首先,探究了图案化取向场和旋涂条件对近晶相液晶拓扑超结构的形态与大小的操控;然后,验证了焦锥畴超结构的微透镜成像功能,并通过材料复合优化和引入聚合物稳定策略,实现了正方焦锥畴阵列在35℃下(向列相)的电刺激动态调控性能;最后,研究了手性、光场和热场对双相态液晶超结构带来的多维度调控.本研究充分利用光取向场、聚合物网络、电场、手性、光场等多元外场刺激,实现了对近晶相液晶多层级超结构的多维度调控.
Modulation of smectic liquid crystals superstructures under multiple external fields
Making full use of the self-assembly and stimulus-response properties of liquid crystals(LCs)to achieve flexible construction,dynamic manipulation and multi-functional applications of smectic LC hierachical superstructures has great significance for stimulating more cutting-edge innovative devices and pushing the practical application of LC superstructures.This research focuses on preparation and self-assembly of smectic LC superstructures,modulation of defect structures by multiple external stimuli,and dynamic regulation laws.First,the shape and size modulation of smectic LC topological superstructures by photopatterning and spin-coating parameters were explored.Then,the microlensing function of the focal conic domain arrays was verified.Through optimization of composite material and proposing the polymer-stabilized strategy,dynamic regulation of the square focal cone domain array under electric field at 35℃(i.e.,nematic phase)was demonstrated.Finally,this paper also studied multi-dimensional control of smectic LC topological superstructures by introducing chirality,light field and thermal field.This study combines multiple external field stimuli,such as photoalignment,film thickness,polymer network,electric field,chirality,and light field to achieve multi-dimensional control of the hierachical superstructure of smectic LCs.

liquid crystalsmectic phasephotoalignmentsuperstructuredynamic controlchirality

张涵、王龙洋、朱柏翰、王泽宇、魏阳、马玲玲、陆延青

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南京大学 现代工程与应用科学学院,江苏 南京 210093

液晶 近晶相 光控取向 超结构 动态调控 手性

国家重点研发计划国家重点研发计划国家自然科学基金江苏省自然科学基金江苏省基础研究计划

2022YFA14050002021YFA120200062375119BK20212004BK20232040

2024

液晶与显示
中科院长春光学精密机械与物理研究所 中国光学光电子行业协会液晶分会 中国物理学会液晶分会

液晶与显示

CSTPCD北大核心
影响因子:0.964
ISSN:1007-2780
年,卷(期):2024.39(3)
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