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原位吸附技术修复六价铬污染土壤

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常见六价铬Cr(Ⅵ)污染场地修复技术如客土法、还原法、固化法、生物法等存在成本高、效率低及Cr(Ⅵ)被二次氧化等缺点.理想修复技术应能快速、低成本地将铬元素(Cr)从土壤中彻底去除.本文将聚吡咯(PPy)通过原位聚合的方式负载在凹凸棒土(ATP)表面,制备了以PPy为"壳"和以ATP为"核"的ATP/PPy复合材料,ATP/PPy对Cr(Ⅵ)的最大吸附容量为 185.19mg/g,吸附机理包括静电引力、螯合、还原与离子交换等.将ATP/PPy嵌入土壤中,利用Cr(Ⅵ)在土壤中的纵向迁移及横向浓度差渗透,可实现对土壤中Cr(Ⅵ)的原位吸附.实验考察了模拟降雨量、土壤pH、土壤容重、土壤有机质含量等因素对土壤中Cr(Ⅵ)去除效率的影响.结果表明,当供试土壤中Cr(Ⅵ)浓度为 30mg/kg,模拟降雨量为 6mL/天,土壤有机质含量为 7.6g/kg,土壤容重为 1.22g/cm3,土壤pH为 5.86时,第 35天时土壤滤液中Cr(Ⅵ)去除率为58.51%,土壤中Cr(Ⅵ)含量降低至2.97mg/kg,低于《土壤环境质量建设用地土壤污染风险管控标准(试行)》(GB36600-2018)中的建设用地第二类用地筛选值 5.7mg/kg.该技术具有操作简单、经济环保、效率高、去除彻底等优势,可为污染场地的高效低成本治理提供新思路及技术支撑.
In situ Adsorption Technology for Remediation of Cr(Ⅵ)Contaminated Soil
The commonly used remediation technologies for Cr(Ⅵ)contaminated soil,such as guest soil,reduction,solidification,microbiology,etc.,have drawbacks such as high cost,slow efficiency,and secondary oxidation of Cr(Ⅵ).To solve these problems,a Cr(Ⅵ)contaminated soil remediation technology was developed.Firstly,polypyrrole was loaded onto the surface of attapulgite through in situ polymerization to prepare ATP/PPy adsorption material with PPy as the"shell"and ATP as the"core".Then,ATP/PPy was embedded into the soil and remediate Cr(Ⅵ)contaminated soil through in situ adsorption technology.The experimental results show that under optimal conditions,the removal rate of Cr(Ⅵ)in soil filtrate was 58.51%,and the Cr(Ⅵ)content in the soil was reduced to 2.97mg/kg,which was lowered to below the screening value of 5.7mg/kg for the second category of development land in the Soil Environmental Quality:Risk Control Standard for Soil Contamination of Development Land(GB 36600-2018).Meanwhile,this technology has the advantages of simple operation,economic and environmental protection,high remediation efficiency,and thorough removal,and can be used for the remediation and treatment of actual Cr(Ⅵ)contaminated soil.The BRIEF REPORT is available for this paper at http://www.ykcs.ac.cn/en/article/doi/10.15898/j.ykcs.202307090090.

attapulgitepolypyrrolesoil remediationhexavalent chromiumin situ adsorption

张兆鑫、曹宁宁、李林记、刘素青、李佳昊、曹翠、李和平、张凯、石勇丽

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河南省地质研究院(地质实验测试所),河南郑州 450018

自然资源部黄河流域中下游水土资源保护与修复重点实验室,河南郑州 450052

河南省自然资源科技创新中心(水土生态修复治理研究),河南郑州 450052

凹凸棒土 聚吡咯 土壤修复 六价铬 原位吸附

河南省科技攻关计划河南省科技攻关计划河南省煤田地质局科研项目河南省地质研究院揭榜挂帅项目河南省地质研究院揭榜挂帅项目

2121023100812321023201252023-906-XM012-KT022023-906-XM015-KT05

2024

岩矿测试
中国地质学会岩矿测试技术专业委员会 国家地质实验测试中心

岩矿测试

CSTPCD北大核心
影响因子:1.344
ISSN:0254-5357
年,卷(期):2024.43(2)
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