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精细化在"111"产品质量提升中的应用

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在内蒙古某"CO2+O2"地浸铀矿山引入精细化管理模式,对影响产品质量的吸附、淋洗、酸化沉淀等工序进行精细管理.淋洗剂配制由"沉降母液+碳酸氢钠+盐酸+氯化钠"优化为"沉降母液+碳酸氢钠+清水",维持淋洗剂pH为9.5~10.0,降低了系统氯离子积累;提升淋洗合格液中铀质量峰值浓度,并将其维持在80~130 g/L;自动控制酸化过程的盐酸添加量,精准控制pH在4.5~4.6,进一步降低合格液中的碳铀比;调整淋洗合格液的流量,保持淋洗合格液平均铀质量浓度为30~70 g/L,降低合格液铀质量浓度对产品质量的影响;控制浆体沉淀时间,提升浆体压滤效果.优化生产参数后,产品水分降低了 8.50%,铀含量提升了 2.88%,产品质量整体提升.
Application of Refinement in"111"Product Quality Improvement
The fine management model was introduced in a"CO2+O2"in-situ leaching uranium mine in Inner Mongolia,and the processes of adsorption,leaching,acidification and precipitation which af-fect the quality of production were carefully managed.The preparation of eluent was optimized from"settling mother liquor+sodium bicarbonate+hydrochloric acid+sodium chloride"to"settling mother liquor+sodium bicarbonite+water",the pH of eluent was maintained at 9.5~10.0,and reducing the accumulation of chloride ion in the system.The peak mass concentration of uranium in the eluate was increased and maintained at 80~130 g/L.The amount of hydrochloric acid added in the acidification process is automatically controlled,the pH is accurately controlled in 4.5~4.6,and the ratio of carbon to uranium in the qualified liquid is further reduced.Adjust the flow rate of leachate to keep the average mass concentration of uranium in 30~70 g/L,to reduce the influence of mass con-centration of uranium on product quality.Control slurry precipitation time,to improve slurry pressure filtration effect.After the optimization of production parameters,the moisture content of the product decreased by 8.50%,the uranium content increased by 2.88%,and the product quality was improved as a whole.

refinement"111"productssodium diuranatepressure filtrationelutionproduct quali-tyuranium contentmoisture

刘天印、李喜龙、曹俊鹏、张渤、刘晓奎、冯小刚

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中核通辽铀业有限责任公司,内蒙古通辽 028000

精细化 "111"产品 重铀酸钠 压滤 淋洗 产品质量 铀含量 水分

2024

铀矿冶
中国核学会铀矿冶学会

铀矿冶

CSTPCD
影响因子:0.369
ISSN:1000-8063
年,卷(期):2024.43(2)
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