首页|金属有机框架(MOFs)在超级电容器中的应用与展望

金属有机框架(MOFs)在超级电容器中的应用与展望

扫码查看
随着全球环境污染问题加重,人们需要清洁高效的能源取代化石燃料,因此开发新型绿色储能装置变得越来越重要。超级电容器是介于传统电容器和电池之间的新型电容器,虽然超级电容器比起传统电容器在储能、功率密度和循环性能等方面有所提升,但在可持续的能源转换和储存系统中,探索高稳定性和高容量的新材料仍是一个充满挑战的问题。金属-有机骨架(MOFs)具有的高比表面积和可调节孔径特性,使其成为电催化候选材料并且在超级电容器领域中引起关注。通过文献研究,介绍了几种常见超级电容器如双电层电容器,赝电容和混合电容器及其近些年在超级电容器领域的 MOFs分类:ZIF、IROMFs、MILs、UIOs、HKUST-1 系列和其他近年发现的新型MOFs材料,最后总结了MOFs的研究进展及其优缺点,并对金属有机框架(MOFs)在超级电容器中的发展与挑战进行了讨论。
Application and Prospects of Metal Organic Frames (MOFs) in Supercapacitors
With the worsening global environmental pollution problem,people need clean and efficient energy to replace fossil fuels,so developing new green energy storage devices has become increasingly important.Supercapacitors are a new type of capacitor that lies between traditional ca-pacitors and batteries.Although supercapacitors have improved energy storage,power density,and cycling performance compared to traditional capacitors,exploring new materials with high stability and capacity in sustainable energy conversion and storage systems remains a challenging is-sue.Metal organic frameworks(MOFs),with their high specific surface area and adjustable pore size,have become potential electrocatalytic ma-terials and have attracted attention in the field of supercapacitors.This article mainly introduces several common types of supercapacitors,such as double layer capacitors,pseudo capacitors,and hybrid capacitors,as well as their MOFs classification in the field of supercapacitors in recent years:ZIF,IROMFs,MILs,UIOs,HKUST-1 series,and other new MOFs materials discovered in recent years.Finally,the research progress and advantages and disadvantages of MOFs are summarized.At the same time,in the summary section,the development and challenges of metal or-ganic frameworks(MOFs)in supercapacitors are discussed in conjunction with literature.

MOFsmechanochemical methodgreen chemistry

张悦、王凤武

展开 >

安徽理工大学 化学工程学院, 安徽 淮南 232001

淮南师范学院 化学与材料工程学院, 安徽 淮南 232038

MOFs 超级电容器 电化学

国家自然科学基金

21176099

2024

云南化工
云南省化工研究院 云天化集团有限责任公司 云南煤化工集团有限公司 云南省化学化工学会

云南化工

影响因子:0.272
ISSN:1004-275X
年,卷(期):2024.51(2)
  • 44