首页|半干法制备千克量级α-半水石膏粉及工艺能耗计算

半干法制备千克量级α-半水石膏粉及工艺能耗计算

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以磷石膏、脱硫石膏为原料,采用半干法工艺实现α-半水石膏粉千克量级制备试验,采用SEM场发射扫描电镜和马尔文激光粒度仪分析α-半水石膏粉形貌和粒径分布,对两种α-半水石膏粉物相组成分析和力学性能强度进行对比。结果表明:两种α-半水石膏粉中半水石膏相转化率在90%左右,晶体长径比接近于1,磷石膏基α-半水石膏粉力学性能最佳,其2h抗折强度2。6 MPa,绝干抗压强度13。6 MPa。计算半干法工艺能耗,与传统煅烧法对比能耗降低约29。5%,工艺简单、绿色化,证明半干法工艺量产制备α-半水石膏粉在工业上可行性,为大规模消耗利用化学石膏提供科学基础。
Preparation of Kilogram Scale α-Hemihydrate Gypsum Powder Using Semi Dry Method and its Process Energy Consumption Calculation
This article uses phosphogypsum and desulfurization gypsum as raw materials and adopts a semi dry process to achieve preparation ex-periment of α-hemihydrate gypsum powder at the kilogram level.Using SEM field emission scanning electron microscopy and Malvin laser par-ticle size analyzer,morphology and particle size distribution of α-semi hydrated gypsum powder were analyzed.Two types of α-phase compo-sition analysis and mechanical property strength of semi hydrated gypsum powder were compared.The results indicate that the conversion rate of hemihydrate gypsum phase in hemihydrate gypsum powder is about90%,and the aspect ratio of crystals is close to1.The mechanical properties of phosphite based gypsum α-hemihydrate gypsum powder are the best,with a 2-hour flexural strength of 2.6 MPa and an absolute dry com-pressive strength of 13.6 MPa.Calculating the energy consumption of the semi dry process,compared with the traditional calcination method,the energy consumption is reduced by about 29.5%.The process is simple and green,proving the feasibility of the mass production preparation of the semi dry process of α-semi hydrated gypsum powder in industry.

α-hemihydrate gypsumsemi dry methodkilogram scalephase compositionM =mechanical propertiesenergy consumption

胡增来、胡勇、杜本康、王训彦、王海洋、曹宏、赵明星

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武汉工程大学,湖北 武汉 430205

安徽六国化工股份有限公司,安徽 铜陵 244023

α-半水石膏 半干法 千克量级 相组成 力学性能 能耗

武汉工程大学磷资源开发利用教育部工程研究中心基金

LKF202302

2024

云南化工
云南省化工研究院 云天化集团有限责任公司 云南煤化工集团有限公司 云南省化学化工学会

云南化工

影响因子:0.272
ISSN:1004-275X
年,卷(期):2024.51(2)
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