云南化工2024,Vol.51Issue(2) :26-30.DOI:10.3969/j.issn.1004-275X.2024.02.07

半干法制备千克量级α-半水石膏粉及工艺能耗计算

Preparation of Kilogram Scale α-Hemihydrate Gypsum Powder Using Semi Dry Method and its Process Energy Consumption Calculation

胡增来 胡勇 杜本康 王训彦 王海洋 曹宏 赵明星
云南化工2024,Vol.51Issue(2) :26-30.DOI:10.3969/j.issn.1004-275X.2024.02.07

半干法制备千克量级α-半水石膏粉及工艺能耗计算

Preparation of Kilogram Scale α-Hemihydrate Gypsum Powder Using Semi Dry Method and its Process Energy Consumption Calculation

胡增来 1胡勇 1杜本康 1王训彦 1王海洋 1曹宏 1赵明星2
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作者信息

  • 1. 武汉工程大学,湖北 武汉 430205
  • 2. 安徽六国化工股份有限公司,安徽 铜陵 244023
  • 折叠

摘要

以磷石膏、脱硫石膏为原料,采用半干法工艺实现α-半水石膏粉千克量级制备试验,采用SEM场发射扫描电镜和马尔文激光粒度仪分析α-半水石膏粉形貌和粒径分布,对两种α-半水石膏粉物相组成分析和力学性能强度进行对比.结果表明:两种α-半水石膏粉中半水石膏相转化率在90%左右,晶体长径比接近于1,磷石膏基α-半水石膏粉力学性能最佳,其2h抗折强度2.6 MPa,绝干抗压强度13.6 MPa.计算半干法工艺能耗,与传统煅烧法对比能耗降低约29.5%,工艺简单、绿色化,证明半干法工艺量产制备α-半水石膏粉在工业上可行性,为大规模消耗利用化学石膏提供科学基础.

Abstract

This article uses phosphogypsum and desulfurization gypsum as raw materials and adopts a semi dry process to achieve preparation ex-periment of α-hemihydrate gypsum powder at the kilogram level.Using SEM field emission scanning electron microscopy and Malvin laser par-ticle size analyzer,morphology and particle size distribution of α-semi hydrated gypsum powder were analyzed.Two types of α-phase compo-sition analysis and mechanical property strength of semi hydrated gypsum powder were compared.The results indicate that the conversion rate of hemihydrate gypsum phase in hemihydrate gypsum powder is about90%,and the aspect ratio of crystals is close to1.The mechanical properties of phosphite based gypsum α-hemihydrate gypsum powder are the best,with a 2-hour flexural strength of 2.6 MPa and an absolute dry com-pressive strength of 13.6 MPa.Calculating the energy consumption of the semi dry process,compared with the traditional calcination method,the energy consumption is reduced by about 29.5%.The process is simple and green,proving the feasibility of the mass production preparation of the semi dry process of α-semi hydrated gypsum powder in industry.

关键词

α-半水石膏/半干法/千克量级/相组成/力学性能/能耗

Key words

α-hemihydrate gypsum/semi dry method/kilogram scale/phase composition/M =mechanical properties/energy consumption

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基金项目

武汉工程大学磷资源开发利用教育部工程研究中心基金(LKF202302)

出版年

2024
云南化工
云南省化工研究院 云天化集团有限责任公司 云南煤化工集团有限公司 云南省化学化工学会

云南化工

影响因子:0.272
ISSN:1004-275X
参考文献量13
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