云南化工2024,Vol.51Issue(2) :31-36.DOI:10.3969/j.issn.1004-275X.2024.02.08

核桃壳基活性炭的热性能及其Cr(Ⅵ)吸附特性

Thermal Analysis and Treatment of Cr(Ⅵ) from Wastewater by Walnut Shell Activated Carbon

库尔班江·努尔麦提 热娜古丽·阿不都热合曼
云南化工2024,Vol.51Issue(2) :31-36.DOI:10.3969/j.issn.1004-275X.2024.02.08

核桃壳基活性炭的热性能及其Cr(Ⅵ)吸附特性

Thermal Analysis and Treatment of Cr(Ⅵ) from Wastewater by Walnut Shell Activated Carbon

库尔班江·努尔麦提 1热娜古丽·阿不都热合曼1
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作者信息

  • 1. 喀什大学 化学与环境科学学院, 新疆 喀什 844000
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摘要

用农业废弃物核桃壳制备的活性炭(WSAC)吸附处理六价铬,可达到以废治废效果.对核桃壳基活性炭(WSAC)表面结构进行红外光谱表征,测定其热重、差热等参数的变化,分析其热性质以及热稳定性.考察影响吸附热力学的参数,包括含Cr(Ⅵ)模拟废液的pH、Cr(Ⅵ)初始质量浓度以及 WSAC 投加量对Cr(Ⅵ)吸附去除率的影响.结果显示,影响WSAC吸附六价铬参数的最优值分别为:Cr(Ⅵ)初始浓度为4 mg/L、pH = 3.95、WSAC投加量为2 mg/mL.Cr(Ⅵ)去除率影响因素分析表明,WSAC投加量对Cr(Ⅵ)去除率的影响最大,其次为溶液pH及初始浓度.

Abstract

Walnut shell activated carbon (WSAC) adsorbed Cr(Ⅵ) from wastewater to attain the waste control by the waste.IR Spectroscopy was characterized,TG and DTA was measured and analyzed for WSAC.The effect of pH of Cr(Ⅵ) containing water,Cr(Ⅵ) initial concentration and dosage of WSAC to the efficiency of chromium treatment was investigated,results show that the optimal value of initial concentration,pH and the dosage of WSAC for the adsorption treatment is4 mg/L,3.95,2 mg/mL respectively.Analysis shows that the dosage of WSAC is the essen-tial factor for the Cr(Ⅵ) removing,and pH and Cr(Ⅵ) initial concentration are ranked in behind.

关键词

吸附//活性炭/核桃壳

Key words

adsorption/chromium/activated carbon/walnut shell

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基金项目

喀什大学校级课题(20202699)

出版年

2024
云南化工
云南省化工研究院 云天化集团有限责任公司 云南煤化工集团有限公司 云南省化学化工学会

云南化工

影响因子:0.272
ISSN:1004-275X
参考文献量15
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