云南化工2024,Vol.51Issue(2) :58-61.DOI:10.3969/j.issn.1004-275X.2024.02.14

接枝共聚法改性花生壳纤维素条件优化

Optimization of Modified Peanut Shell Cellulose by Grafting Copolymerization

冯庆玲 叶招权 林继辉 谢勇武
云南化工2024,Vol.51Issue(2) :58-61.DOI:10.3969/j.issn.1004-275X.2024.02.14

接枝共聚法改性花生壳纤维素条件优化

Optimization of Modified Peanut Shell Cellulose by Grafting Copolymerization

冯庆玲 1叶招权 1林继辉 1谢勇武1
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作者信息

  • 1. 闽南科技学院 生命科学与化学学院, 福建 南安 362311
  • 折叠

摘要

花生壳中富含纤维素,是制备纤维素吸附材料的良好来源.通过氢氧化钠-亚氯酸钠法提取花生壳中的纤维素,并以丙烯酰胺为单体、硝酸铈铵为引发剂对花生壳纤维素进行接枝共聚改性,以吸附溶液中Cd2+的量为考察指标,考察丙烯酰胺用量、硝酸铈铵用量、反应温度、反应时间四个因素对改性效果的影响.结果表明:在接枝共聚反应体系中添加6g丙烯酰胺单体,0.3 g硝酸铈铵,55℃条件下反应4h,得到的改性花生壳纤维素对水溶液中Cd2+的吸附效果最好,吸附量为 13.741 mg/g.以此为基础,优化吸附条件将进一步提高吸附率,扩大了废弃花生壳的应用范围.

Abstract

Peanut shell is rich in cellulose,so it is a good source for preparing cellulose adsorption materials.In this paper,cellulose from pea-nut shell was extracted by sodium hydroxide-sodium chlorite method,and the peanut shell cellulose was grafted with acrylamide as monomer and ammonium cerium nitrate as initiator.The amount of Cd2+ in the adsorption solution was used as the index to investigate the effects of the a-mount of acrylamide,ammonium cerium nitrate,reaction temperature and reaction time on the modification effect.The results showed that the modified peanut shell cellulose obtained by adding 6 g acrylamide monomer and 0.3 g ammonium cerium nitrate to the graft copolymerization sys-tem had the best adsorption effect on Cd2+ in aqueous solution at 55℃for 4 h,and the adsorption capacity was 13.741 mg/g.On this basis,optimization of the adsorption process will further improve the adsorption rate and expand the application range of waste peanut shells.

关键词

接枝共聚法/花生壳纤维素/改性条件优化

Key words

grafting copolymerization/peanut shell cellulose/optimization of modification conditions

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基金项目

教育厅中青年科技项目(JAT210618)

出版年

2024
云南化工
云南省化工研究院 云天化集团有限责任公司 云南煤化工集团有限公司 云南省化学化工学会

云南化工

影响因子:0.272
ISSN:1004-275X
参考文献量13
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