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中山市一次臭氧污染过程分析

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2022 年4 月4-8 日中山市发生连续臭氧(O3)污染过程,其中6 日为中度污染.污染期间,O3 前体物挥发性有机物(VOCs)和NO2 均明显上升,"光化学燃料"充足,太阳辐射强度亦高于非污染日,加剧光化学反应,O3 以本地生成为主.污染期间和清洁时段的O3、NO2 和VOCs的日变化呈现相似的趋势,污染日的O3、NO2和VOC均高于非污染日,O3 呈现午后高峰、VOCs和NO2 则为双峰分布.进行活性物种分析,O3 生成潜势排名靠前的物种为要为甲苯类和正丁烷,主要来源于工业溶剂和机动车尾气.中山市此次污染的主要为前体物升高及气象条件不利所致,主要活性物种来自于溶剂源,因此在气象不利的条件下,须提前预警,做好VOCs管控.
Analysis of an Ozone Pollution Process in Zhongshan
A continuous ozone(O3)pollution process occurred in Zhongshan City from April 4 to 8,2022,with moderate pollution on April 6.During the pollution period,the ozone precursors volatile organic compounds(VOCs)and NO2 are significantly increased,"photochemical fuel"is sufficient.The intensity of solar radiation also higher than the clean period,which intensifies the photochemical reaction,and O3 is mainly generated locally.The diurnal variation of O3,NO2 and VOCs during the pollution period and the clean period showed a similar trend,and the O3,NO2 and VOC on the pollution day were higher than those on the non-pollution day,while the O3 showed an afternoon peak and the VOC and NO2 showed a bimodal distribution.According to the analysis of active species,the species with the highest O3 generating potential are tolu-ene,olefin and n-butane,which mainly come from industrial solvents,motor vehicle exhaust and plant emissions.The pollution in Zhongshan City is mainly caused by the rise of precursors and adverse meteorological conditions,and the main active species come from the solvent source,so under adverse meteorological conditions,it is necessary to warn in advance and do a good job of VOCs control.

ozonevolatile organic compoundsozone formation potentialpollution process

黄艳梅、翟宇虹

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无锡中科光电技术有限公司, 江苏 无锡 214135

广东省生态环境监测中心, 国家环境保护区域空气质量监测重点实验室, 广东 广州 510308

臭氧 挥发性有机物 臭氧生成潜势 污染过程

2024

云南化工
云南省化工研究院 云天化集团有限责任公司 云南煤化工集团有限公司 云南省化学化工学会

云南化工

影响因子:0.272
ISSN:1004-275X
年,卷(期):2024.51(2)
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