云南化工2024,Vol.51Issue(2) :141-144.DOI:10.3969/j.issn.1004-275X.2024.02.33

焦炉煤气GLT络合铁脱硫绿色低碳系统性解决方案分析

Analysis of Green and Low Carbon Systematic Solution for Desulfurization of Coke Oven Gas from GLT Chelated Iron

余国贤 胡璐 徐勋达 潘威
云南化工2024,Vol.51Issue(2) :141-144.DOI:10.3969/j.issn.1004-275X.2024.02.33

焦炉煤气GLT络合铁脱硫绿色低碳系统性解决方案分析

Analysis of Green and Low Carbon Systematic Solution for Desulfurization of Coke Oven Gas from GLT Chelated Iron

余国贤 1胡璐 2徐勋达 2潘威2
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作者信息

  • 1. 江汉大学 化工系, 湖北 武汉 430056
  • 2. 武汉国力通能源环保股份有限公司, 湖北 武汉 430206
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摘要

焦炉煤气PDS脱硫的硫磺收率在 50%~60%,副盐累积产生大量脱硫废液,仅仅络合铁催化剂应用在HPF装置上存在诸多问题.从GLT络合铁脱硫的化学原理和工艺原理出发,结合工业改造实际,GLT络合铁技术应用在焦炉煤气净化中形成了系统化成套解决方案,不仅解决了络合铁催化剂应用的适配性问题,而且将硫膏资源化的同时实现零废液外排.通过案例对比分析了不同技术路线的技术经济性,GLT络合铁技术系统性解决焦炉煤气脱硫存在的环保问题,显著节省投资和运行费用,极大降低煤气净化过程的二氧化碳排放.

Abstract

Sulfur yield of PDS desulfurization of coke oven gas is50%-60%,and a large amount of desulfurization waste liquid is generated by accumulation of by-salts.Based on the chemical principle and technological principle of GLT chelated iron desulfurization,combined with the actual industrial transformation,the application of GLT chelated iron technology in coke oven gas purification has formed a systematic complete set of solutions,which not only solves the suitability problem of the application of chelated catalyst,but also realizes zero waste liquid discharge while the sulfur paste is recycled.By comparing and analyzing the technical economy of different technical routes,GLT chelated iron technology systematically solves the environmental problems existing in coke oven gas desulfurization,significantly saves investment and operating costs,and greatly reduces carbon dioxide emissions in the process of the gas purification.

关键词

焦炉煤气/脱硫/络合铁/绿色低碳/解决方案

Key words

coke oven gas/desulfurization/chelated iron/green and low carbon/solution

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出版年

2024
云南化工
云南省化工研究院 云天化集团有限责任公司 云南煤化工集团有限公司 云南省化学化工学会

云南化工

影响因子:0.272
ISSN:1004-275X
参考文献量6
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