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过硫酸钾与盐酸制取氯气的最佳条件探索

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针对目前实验室用MnO2 与浓HCl反应制取氯气实验存在反应物用量没有说明,反应原理学生不易理解,现象不明显等缺陷,提出了实验室用 K2S2O8 与 HCl 反应制备氯气,并利用正交试验法探讨了实验室用K2S2O8 与HCl反应制取氯气的最佳工艺条件.实验表明:用K2S2O8 与HCl反应制取氯气,避免了MnO2 与浓HCl共热制取氯气实验中的缺陷,且实验现象明显,反应速率适中,完全满足了课堂演示和学生实验的要求.因此,建议中学化学教学中选用该方法为制备氯气的课堂演示实验或学生实验.
Exploration of the Optimal Conditions for Producing Chlorine Gas by Reacting Potassium Persulfate with Hydrochloric Acid in the Laboratory
In response to the shortcomings of the current laboratory experiment using MnO2 to react with concentrated HCl to produce chlorine gas,such as the lack of explanation of reactant dosage,difficulty for students to understand the reaction principle,and unclear phenomena,a la-boratory experiment using K2S2O8 to react with HCl to produce chlorine gas was proposed.The orthogonal experimental method was used to ex-plore the optimal process conditions for the reaction of K2S2O8 with HCl to produce chlorine gas in the laboratory.The experiment shows that u-sing K2S2O8 and HCl to produce chlorine gas avoids the defects in the experiment of co heating MnO2 with concentrated HCl to produce chlorine gas.At the same time,the phenomenon is obvious during the experiment,and the reaction rate is moderate,fully meeting the requirements of classroom demonstrations and student experiments.Therefore,it is recommended to use this method in middle school chemistry teaching as a classroom demonstration experiment or a student experiment for preparing chlorine gas.

chlorine gas preparationpotassium persulfate and hydrochloric acidoptimum conditionsorthogonal experiment

吴佳鑫、丁浩栋、吴嘉欣、梁永锋

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宁夏师范学院 化学化工学院, 宁夏 固原 756000

氯气制备 过硫酸钾与盐酸 最佳条件 正交试验

宁夏回族自治区无机化学"一流课程"建设项目宁夏师范学院一流基层教学组织建设项目

NXYLKC201906NSYLJYS202006

2024

云南化工
云南省化工研究院 云天化集团有限责任公司 云南煤化工集团有限公司 云南省化学化工学会

云南化工

影响因子:0.272
ISSN:1004-275X
年,卷(期):2024.51(3)
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