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某有机化工厂废水中水回用案例工艺及运行分析

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采用"臭氧催化氧化+硝化反硝化生化系统+浸没式超滤+反渗透"组合工艺深度处理有机化工废水(该深化处理系统进水为预处理阶段的出水),实现废水的再回收利用.工程处理规模为360 m3/d,其中生化部分出水COD平均值为79 mg/L,NH3-N在0.1~0.8 mg/L之间,TN值稳定在15 mg/L左右,各指标均满足反渗透两倍浓缩要求(即浓水纳管排放标准);回用水水质COD ≤5 mg/L,NH3-N≤0.1 mg/L,Cl-≤3.5 mg/L,电导率≤10 μS/cm,pH 7.3~8.6,回用率≥50%,符合回用水水质及水量要求.实践表明,该深化处理中水回用系统运行稳定,既能达到企业节约水资源的目的,又能实现中水回用的要求.
Process and Operation Analysis of a Case Study on Water Reuse in Organic Chemical Waste water
In order to realize the recycling of wastewater,the project adopted the combined process of"ozone catalytic oxidation+nitrification and denitrification biochemical system+submerged ultrafiltration+reverse osmosis"to deeply treat organic chemical wastewater,which was the outlet water in the pretreatment stage.The scale of engineering treatment was 360 m3/d,the average value of COD of effluent from biochemi-cal part was 79 mg/L,the NH3-N was between 0.1-0.8 mg/L,the TN value was stable at about 15 mg/L,and all indicators met the concen-trated water pipe discharge standard requirements of reverse osmosis double concentration.Reuse water quality:COD≤5 mg/L,NH3-N≤0.1 mg/L,Cl-≤3.5 mg/l,conductivity≤10 μs/cm,pH 7.3~8.6,reuse rate ≥50%,meeting the requirements of reuse water quality and quan-tity.The practice results showed that the deepening treatment of reclaimed water reuse system operated stably,which could not only achieve the purpose of saving water resources,but also meet the requirements of reclaimed water reuse.

Organic ChemicalsAdvanced TreatmentReverse OsmosisReclaimed Water Reuse

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中煤科工集团杭州研究院有限公司,浙江 杭州 311201

有机化工 深度处理 反渗透 中水回用

2024

云南化工
云南省化工研究院 云天化集团有限责任公司 云南煤化工集团有限公司 云南省化学化工学会

云南化工

影响因子:0.272
ISSN:1004-275X
年,卷(期):2024.51(4)
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