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一种咔唑基二氟化硼配合物的合成及光学性能研究

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咔唑是良好的空穴传输基团,将具有供电子特性的三苯胺基团与具有吸电子特性的二氟化硼单元引入咔唑基体中,获得一种新型的咔唑基二氟化硼配合物,并对合成的物质进行核磁表征和光学性能测试.结果表明,该配合物具有分子内电荷转移特性、聚集诱导发射活性和固体荧光行为.
Research on Synthesis and Optical Properties of a Novel Carbazole-based Difluoroboron Complex
Carbazole was a excellent hole transport group,we introduced the triphenylamine group with the electron-donating property and the difluoroboron unit with the electron-withdrawing feature into carbazole skeleton to obtain a novel cabazole-based difluoroboron complex.And the synthesized complex was performed on nuclear magnetic resonance characterization and optical performance measurement.The testing results indicated that the synthesized complex exhibited intramolecular charge transfer characteristics,aggregation-induced emission activity,and sol-id-state fluorescence behavior.

CarbazoleDifluoroboron ComplexAggregation-induced Emission

李先、窦思虎、田佳壮、高树林、杨艳华

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昆明学院 化学化工学院,云南 昆明 650214

咔唑 二氟化硼配合物 聚集诱导发射

2024

云南化工
云南省化工研究院 云天化集团有限责任公司 云南煤化工集团有限公司 云南省化学化工学会

云南化工

影响因子:0.272
ISSN:1004-275X
年,卷(期):2024.51(9)