云南化工2024,Vol.51Issue(11) :46-50.DOI:10.3969/j.issn.1004-275X.2024.11.11

真空紫外/紫外/芬顿组合工艺处理抗生素制药废水的研究

Removal of Betamethasone from Pharmaceutical Wastewater by Vacuum UV/UV Process-

薛福海 杨腊祥
云南化工2024,Vol.51Issue(11) :46-50.DOI:10.3969/j.issn.1004-275X.2024.11.11

真空紫外/紫外/芬顿组合工艺处理抗生素制药废水的研究

Removal of Betamethasone from Pharmaceutical Wastewater by Vacuum UV/UV Process-

薛福海 1杨腊祥1
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作者信息

  • 1. 邵阳学院 食品与化学工程学院,湖南 邵阳 422000
  • 折叠

摘要

随着人们对抗生素药物用量需求的逐年上升,其生产过程中产生的制药废水对自然环境的影响也日趋显著.研究了真空紫外/紫外/芬顿(VUV/UV/Fenton)组合工艺对抗生素制药废水中磺胺氯哒嗪(SCP)的降解效果,考察了不同影响因素对SCP去除的影响.结果表明,在室温(25 ℃)条件下,pH为6,Fe2+浓度为0.5 mmol/L,H2O2浓度为12.5 mmol/L时,SCP降解效果最佳,降解率在25 min内达到了 100%.在VUV/UV/Fenton工艺中,Fe2+和H2O2的浓度比为1∶25,比传统Fenton工艺减少了 H2O2的投入.无机氯离子、硝酸根离子和硫酸根离子对SCP的降解影响很小(<2.2%).VUV/UV/Fenton工艺对抗生素废水处理十分有效.

Abstract

With the increasing demand for antibiotic drugs,the impact of pharmaceutical wastewater produced in the production process on the natural environment is becoming more and more significant.In this paper,the degradation effect of VUV/UV/Fenton combined process on sul-fonamide chlorpyridazine(SCP)in antibiotic pharmaceutical wastewater was studied,and the influence of different influencing factors on SCP removal was investigated.The results showed that at room temperature(25 ℃),pH=6,Fe2+concentration of 0.5 mM,H2O2 concentration of 12.5 mM,the degradation effect was the best,and the degradation rate reached 100%in 25 min.In the VUV/UV/Fenton process,the concentra-tion ratio of Fe2+and H2O2 is 1∶25,which greatly reduces the input of H2O2 content compared with the traditional Fenton process.Inorganic chlo-ride ions,nitrate ions and sulfate ions had little effect on SCP degradation(<2.2%).Therefore,VUV/UV/Fenton process is very effective for the treatment of antibiotic wastewater.

关键词

磺胺氯哒嗪/抗生素制药废水/VUV/UV/Fenton/影响因素

Key words

Sulfachlorpyridazine/Antibiotic/Wastewater/VUV/UV/Fenton

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出版年

2024
云南化工
云南省化工研究院 云天化集团有限责任公司 云南煤化工集团有限公司 云南省化学化工学会

云南化工

影响因子:0.272
ISSN:1004-275X
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