云南化工2024,Vol.51Issue(11) :101-102.DOI:10.3969/j.issn.1004-275X.2024.11.22

玻璃熔片-X射线荧光光谱法快速测定电池用磷酸铁产品中的磷和铁

Rapid Determination of Phosphorus and Iron in Iron Phosphate Products for Battery Matreials by Glass Frit-X-ray Fluorescence Spectrometry

张江坤 欧志兵 史鑫 王正南
云南化工2024,Vol.51Issue(11) :101-102.DOI:10.3969/j.issn.1004-275X.2024.11.22

玻璃熔片-X射线荧光光谱法快速测定电池用磷酸铁产品中的磷和铁

Rapid Determination of Phosphorus and Iron in Iron Phosphate Products for Battery Matreials by Glass Frit-X-ray Fluorescence Spectrometry

张江坤 1欧志兵 1史鑫 1王正南1
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作者信息

  • 1. 云南磷化集团有限公司,云南 昆明 650600
  • 折叠

摘要

通过玻璃熔片-X射线荧光光谱法对电池用磷酸铁产品中磷和铁含量的测定进行了探究,采用理论a系数矫正后线性回归方程相关系数达0.9996,线性良好,P相对标准偏差(RSD)为0.24%,Fe相对标准偏差(RSD)为0.12%,结果表明,方法有较好的精密度、准确度,检测快速、操作简便,适合于磷酸铁产品中磷和铁含量的快速测定.

Abstract

This article explores the determination of phosphorus and iron content in battery materials lithium iron phosphate products using the glass fusion bead-X-ray fluorescence spectrometry method.After applying the theoretical alpha coefficient correction,the correlation coefficient of the linear regression equation reaches 0.9996,indicating excellent linearity.The relative standard deviation(RSD)for phosphorus(P)is 0.24%,and for iron(Fe)it is 0.12%.The experiment results demonstrates that this method offers good precision and accuracy,with rapid de-tection and easy operation,making it suitable for the rapid determination of phosphorus and iron content in lithium iron phosphate products.

关键词

玻璃熔片/X射线荧光光谱法///磷酸铁

Key words

Glass Frit/X-ray Fluorescence Spectrometry/Phosphorus/Iron/Iron Phosphate

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出版年

2024
云南化工
云南省化工研究院 云天化集团有限责任公司 云南煤化工集团有限公司 云南省化学化工学会

云南化工

影响因子:0.272
ISSN:1004-275X
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