首页|基于HS-SPME-GC/MS的丁香与肉桂复配前后物质变化分析

基于HS-SPME-GC/MS的丁香与肉桂复配前后物质变化分析

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以方剂"丁桂散"为依据,探究丁香、肉桂复配前后挥发性物质的变化.研究采用顶空-固相微萃取-气相色谱/质谱联用技术,结合统计学方法对丁香、肉桂及复配物的挥发性物质进行比较分析.从丁香、肉桂及复配物中分别鉴定出60种,55种,61种挥发性化学成分;共有的挥发性成分有31种,分别占其总量的444.84‰、666.63‰、505.51‰.存在于丁香、肉桂中的13种、10种挥发性成分未在复配物中检出,复配后挥发性物质的种类上没有变化,但复配物的挥发性物质含量占比,相较于复配前的单个原料发生了显著的变化.不同复配比例下"丁桂散"的欧式距离相似度存在线性关系y=-0.375x+0.423,R2=0.993,且丁香对复配后挥发性物质的影响占主导地位.
Analysis of substance changes of clove and cinnamon before and after blending based on HS-SPME-GC/MS
Based on the prescription"Dingguisan",the changes of volatile components before and after the blending of cloves and cinnamon were studied.Headspace-Solid Phase Micro-Extraction-Gas Chromatography/Mass Spectrometry(HS-SPME-GC/MS)combined with statistical methods were used to compare and analyze the vola-tile substances of clove,cinnamon and their blends.60 kinds,55 kinds and 61 kinds of volatile components were i-dentified from clove,cinnamon and their blends,respectively.Among the three groups of samples,clove,cinnamon and blend have 31 kinds of volatile componentsin common,accounting for 444.84‰,666.63%oand 505.51‰ of their total content respectively.13 kindsand 10 kinds of volatile components in clove and cinnamon were not detec-ted in the blend.The results showed that there was no change in the types of volatile substances after blending.However,the proportion of volatile substances content in the blend has changed significantly compared with the sin-gle raw material before blending.There was a linear relationship between the similarity of Euclidean distance of"Dingguisan"with different blending ratios,y=-0.375x+0.423,R2=0.993,and clove had a dominant effect on the volatile substances after blending.

clovecinnamonblendHS-SPME-GC/MSvolatile components

黄德全、张海瑜、郑君娜、陈建华、王晋、李银科、张承明

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云南民族大学民族医药学院,云南昆明 650504

云南中烟工业有限责任公司技术中心,云南昆明 650231

云南民族大学化学与环境学院,云南昆明 650504

丁香 肉桂 复配 HS-SPME-GC/MS 挥发性成分

云南省科技计划云南中烟科技项目

2019HC0202022ZK01

2024

云南民族大学学报(自然科学版)
云南民族大学

云南民族大学学报(自然科学版)

CSTPCD
影响因子:0.381
ISSN:1672-8513
年,卷(期):2024.33(2)
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