油气田地面工程2024,Vol.43Issue(3) :21-27.DOI:10.3969/j.issn.1006-6896.2024.03.004

壳聚糖季铵盐对O/W乳状液的破乳性能评价

Evaluation of Demulsification Performance of Chitosan Quaternary Ammonium Salt on O/W Emulsion

颜廷俊 党新才 王晓和 提浩强 陈家庆 刘帅
油气田地面工程2024,Vol.43Issue(3) :21-27.DOI:10.3969/j.issn.1006-6896.2024.03.004

壳聚糖季铵盐对O/W乳状液的破乳性能评价

Evaluation of Demulsification Performance of Chitosan Quaternary Ammonium Salt on O/W Emulsion

颜廷俊 1党新才 2王晓和 1提浩强 1陈家庆 3刘帅4
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作者信息

  • 1. 北京化工大学特种流体中心
  • 2. 长庆油田分公司西安工业服务处
  • 3. 北京石油化工学院机械工程学院
  • 4. 海洋石油工程股份有限公司
  • 折叠

摘要

以壳聚糖季铵盐作为破乳剂,使用Turbiscan Lab稳定性分析仪实验研究了破乳剂浓度及处理温度对水包油(O/W)型乳状液破乳效果的影响.实验结果表明:在25~55℃的处理温度范围内,破乳剂最佳使用浓度约0.4%(体积分数),破乳剂浓度超过1.0%后,无破乳效果.在操作温度为25℃、破乳剂加药浓度为0.4%时,所测得的背散射光ΔBS曲线显示出良好的油水分层现象,相应的TSI曲线值达到最大,油滴粒径增大 7倍,破乳过程在 10 min之内基本完成.在25~55℃的处理温度范围内,破乳效果随温度升高而改善,最佳破乳温度为55℃.此研究对油田采出液破乳方法的选择具有指导借鉴意义.

Abstract

Using chitosan quaternary ammonium salt as emulsion breaker,the effect of emulsion breaker concentration and treatment temperature on the emulsion breaking effect of oil-in-water(O/W)type emulsion is investigated experimentally using a Turbiscan Lab stability analyzer.The experi-mental results show that the optimum emulsion breaker concentration is around 0.4%(volume fraction)in the treatment temperature range of 25℃~55℃,and the emulsion breaking ability is basically lost af-ter the emulsion breaker concentration exceeds 1.0%.At the operating temperature of 25℃and emul-sion breaker dosing concentration of 0.4%,the measured backscattered light ΔBS curve shows good oil-water delamination,the corresponding TSI curve value reaches the maximum,the oil droplet particle size increases 7 times,and the emulsion breaking process is basically completed within 10 min.In the treatment temperature range from 25℃to 55℃,the emulsion breaking effect improves with the in-creasing temperature,and the best emulsion breaking temperature is 55℃.This study has guiding and reference significance for the selection of demulsification methods for oilfield produced fluids.

关键词

季铵盐破乳剂/加药浓度/温度/乳状液/ΔBS曲线/TSI曲线

Key words

quaternary ammonium emulsion breaker/dosing concentration/temperature/emulsion/ΔBS curve/TSI curve

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基金项目

国家自然科学基金(52074018)

出版年

2024
油气田地面工程
大庆油田有限责任公司

油气田地面工程

影响因子:0.273
ISSN:1006-6896
参考文献量13
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