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壳聚糖季铵盐对O/W乳状液的破乳性能评价

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以壳聚糖季铵盐作为破乳剂,使用Turbiscan Lab稳定性分析仪实验研究了破乳剂浓度及处理温度对水包油(O/W)型乳状液破乳效果的影响.实验结果表明:在25~55℃的处理温度范围内,破乳剂最佳使用浓度约0.4%(体积分数),破乳剂浓度超过1.0%后,无破乳效果.在操作温度为25℃、破乳剂加药浓度为0.4%时,所测得的背散射光ΔBS曲线显示出良好的油水分层现象,相应的TSI曲线值达到最大,油滴粒径增大 7倍,破乳过程在 10 min之内基本完成.在25~55℃的处理温度范围内,破乳效果随温度升高而改善,最佳破乳温度为55℃.此研究对油田采出液破乳方法的选择具有指导借鉴意义.
Evaluation of Demulsification Performance of Chitosan Quaternary Ammonium Salt on O/W Emulsion
Using chitosan quaternary ammonium salt as emulsion breaker,the effect of emulsion breaker concentration and treatment temperature on the emulsion breaking effect of oil-in-water(O/W)type emulsion is investigated experimentally using a Turbiscan Lab stability analyzer.The experi-mental results show that the optimum emulsion breaker concentration is around 0.4%(volume fraction)in the treatment temperature range of 25℃~55℃,and the emulsion breaking ability is basically lost af-ter the emulsion breaker concentration exceeds 1.0%.At the operating temperature of 25℃and emul-sion breaker dosing concentration of 0.4%,the measured backscattered light ΔBS curve shows good oil-water delamination,the corresponding TSI curve value reaches the maximum,the oil droplet particle size increases 7 times,and the emulsion breaking process is basically completed within 10 min.In the treatment temperature range from 25℃to 55℃,the emulsion breaking effect improves with the in-creasing temperature,and the best emulsion breaking temperature is 55℃.This study has guiding and reference significance for the selection of demulsification methods for oilfield produced fluids.

quaternary ammonium emulsion breakerdosing concentrationtemperatureemulsionΔBS curveTSI curve

颜廷俊、党新才、王晓和、提浩强、陈家庆、刘帅

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北京化工大学特种流体中心

长庆油田分公司西安工业服务处

北京石油化工学院机械工程学院

海洋石油工程股份有限公司

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季铵盐破乳剂 加药浓度 温度 乳状液 ΔBS曲线 TSI曲线

国家自然科学基金

52074018

2024

油气田地面工程
大庆油田有限责任公司

油气田地面工程

影响因子:0.273
ISSN:1006-6896
年,卷(期):2024.43(3)
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