首页|锅炉用稠油采出水预处理工艺运行效果评价

锅炉用稠油采出水预处理工艺运行效果评价

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油田稠油采出水成分复杂,具有矿化度高、二氧化硅浓度高的特点,采用常规的稠油污水处理工艺进行处理后,回用到锅炉会造成锅炉内部结垢,影响锅炉安全生产和蒸汽质量.为解决油田注汽锅炉结垢问题,采用污水深度除硅和降盐处理技术,而反渗透膜的给水要求较为苛刻,净化软化后的稠油污水进入反渗透膜容易造成反渗透膜的污堵,除盐效果不稳定.分析得出反渗透膜结垢影响因素为水中的有机物、二氧化硅、铝离子.在常规的稠油污水处理工艺基础上,增加了污水混凝除硅、微絮凝过滤、超滤处理工艺,使COD(化学需氧量)从419.8 mg/L降至201.5 mg/L、二氧化硅从质量浓度333.9 mg/L降至39.6 mg/L、铝离子质量浓度从0.268 mg/L降至0.032 mg/L,使反渗透膜给水SDI(污染指数)小于5、浊度小于1 NTU、反渗透膜产水电导率小于2 000 μs/cm,提高了注汽锅炉给水水质,提升了锅炉蒸汽质量,解决了油田注汽锅炉结二氧化硅垢和盐垢的问题.
Evaluation of Operating Effect of Pretreatment Process of Oilfield Heavy Oil Produced Water Reused in Boiler
The composition of the produced water of heavy oil in oilfields is complex,with high sa-linity and high concentration of silica.Heavy oil produced water is treated by conventional heavy oil sewage treatment process,and reused in the boiler,which causes scaling inside the boiler,and affects the safety production and steam quality of the boiler.In order to solve the scaling problem of oilfield steam injection boiler,the technology of deep silicon removal and salt reduction of sewage is adopted.However,the water supply requirement of reverse osmosis membranes is relatively strict,purified and softened heavy oil sewage entering the reverse osmosis membrane can easily cause fouling and blockage of the membrane,and the effect of salt removal is unstable.The influencing factors of scale formation in reverse osmosis membranes are analyzed as organic matter,silica,and aluminum ions in water.Based on the conventional heavy oil sewage treatment process,sewage coagulation and silicon removal,mi-cro-flocculant filtration,and ultrafiltration are added.The COD is reduced from 419.8 mg/L to 201.5 mg/L,the mass concentration of silica is reduced from 333.9 mg/L to 39.6 mg/L,the mass concentra-tion of aluminum ions is reduced from 0.268 mg/L to 0.032 mg/L.The feed water SDI of the reverse osmosis membrane is less than 5,the turbidity is less than 1NTU,and the conductivity of the reverse osmosis membrane produced water is less than 2000 μs/cm.The water quality of the steam injection boiler is improved,the steam quality of the boiler is improved,and the problem of silica scale and salt scale in the oilfield steam injection boiler is solved.

boiler waterheavy oil sewagereverse osmosisscaling

丁洪雷、周京都、李平原、沙强红

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新疆科力新技术发展股份有限公司

中油(新疆)石油工程有限责任公司

锅炉用水 稠油污水 反渗透 结垢

2024

油气田地面工程
大庆油田有限责任公司

油气田地面工程

影响因子:0.273
ISSN:1006-6896
年,卷(期):2024.43(7)