油气田地面工程2024,Vol.43Issue(10) :21-26.DOI:10.3969/j.issn.1006-6896.2024.10.004

天然气原位再生型液体复合脱硫剂研制

Development of Natural Gas In-situ Regeneration Liquid Compound Desulfurizer

徐明军 尹红卫 孙雪琼 袁野 王钊 李福民 孙广森
油气田地面工程2024,Vol.43Issue(10) :21-26.DOI:10.3969/j.issn.1006-6896.2024.10.004

天然气原位再生型液体复合脱硫剂研制

Development of Natural Gas In-situ Regeneration Liquid Compound Desulfurizer

徐明军 1尹红卫 1孙雪琼 2袁野 1王钊 1李福民 1孙广森3
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作者信息

  • 1. 中国石油塔里木油田公司
  • 2. 中海油信息科技有限公司北京分公司
  • 3. 巴州康菲能源科技有限公司
  • 折叠

摘要

针对油气井钻井完井测试期间作业时间短、搬迁频繁,现有的干法或湿法脱硫工艺需要的设备繁多、工艺复杂、建安周期长及其操作困难的情况,利用自氧化、自还原的特种化合物与变价金属离子催化剂相结合,研制了一种原位再生型液体复合脱硫剂,通过对该脱硫剂的催化剂浓度、pH值、二氧化碳及温度等指标,对脱硫效果的影响进行了实验研究.结果表明:pH值在 8~13间的硫容不低于 330 g/L,在脱硫剂中金属离子催化剂质量浓度不低于 500 mg/L时,脱硫效率大于99.9%,二氧化碳含量小于27%时,对硫容质量分数的影响小于3%;该脱硫剂具有反应快、硫容大、适应性强、选择性强和装填方便的特点,为油气井钻井完井测试期间天然气脱硫提供了一种新手段,为天然气原位再生型液体复合脱硫剂推广应用奠定了基础.

Abstract

In view of the shortcomings of short operation time and frequent relocation during drilling and completion testing of oil and gas wells,the existing dry or wet desulphurization process requires many equipment,complicated process,long construction and installation period,and difficult in operation,a kind of liquid compound desulfurizer with in-situ regeneration is developed by combining the special compound of auto-oxidation and self-reduction with variable valence metal ion catalyst.The influence of catalyst concentration,pH value,carbon dioxide,and temperature of the desulfurizer on the desulfurization effect is experimentally studied.The results show that when the pH value is 8-13,the sulfur capacity is not less than 330 g/L.When the mass concentration of metal ion catalyst in desul-furizer is not less than 500 mg/L,the desulfurization efficiency is greater than 99.9%,and when the carbon dioxide content is less than 27%,the impact on the sulfur capacity mass fraction is less than 3% .The desulfurizer has the characteristics of fast reaction,large sulfur capacity,strong adaptability,strong selectivity,and convenient loading.It provides a new means for natural gas desulfurization during drill-ing and completion testing of oil and gas wells,and lays a foundation for the popularization and applica-tion of in-situ regeneration liquid compound desulfurizer of natural gas.

关键词

天然气/脱硫/液体复合脱硫剂/原位再生/硫容

Key words

natural gas/desulfurization/liquid compound desulfurizer/in-situ regeneration/sulfur capacity

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基金项目

中国石油天然气股份有限公司重大科技专项(2018E-1803)

出版年

2024
油气田地面工程
大庆油田有限责任公司

油气田地面工程

影响因子:0.273
ISSN:1006-6896
参考文献量14
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