首页|20#碳钢在无碱复合驱模拟采出液中腐蚀行为研究

20#碳钢在无碱复合驱模拟采出液中腐蚀行为研究

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无碱复合驱(复合盐、聚合物、表面活性剂)是一种新型改进驱油技术,能够有效降低成本,提高采收率及降低管线结垢.但是,随着集输系统采出液中化学剂浓度逐渐升高,目前,在用的无内防腐20#碳钢材质的集输管道在未来采出液中的适应性还不明确.为摸清20#碳钢材质在采出液中的腐蚀情况,依据大庆油田某区块产能建设工程所提供的无碱复合驱三元上返采出液浓度预测,通过室内模拟现场集输系统工况环境,利用动态腐蚀模拟试验和电化学试验,确定20#碳钢在无碱复合驱模拟采出液中的腐蚀行为.试验结果表明:20#碳钢试片在配制最高浓度模拟液中的腐蚀速率较大,腐蚀等级为中度.目前,区块采出液和回掺水中的腐蚀等级为低度,试片表面在模拟液中出现了明显的钝化现象,但Cl-能够很快穿透钝化膜导致钝化时间较短,加速了腐蚀电极反应.考虑到未来集输管道中采出液里存在的大量Cl-,使电化学反应过程变得更加复杂,将导致管道内腐蚀情况加剧,因此,建议集输管道采取合适的内防腐措施.
Study on Corrosion Behavior of 20#Carbon Steel in Simulated Produced Liquid of Alka-li-free Composite Flooding
The alkali-free composite flooding(compound salt,polymer,and surfactant)is a new and improved technology that can effectively enhance recovery with low-cost and reduce pipeline scal-ing.However,with the gradual increase of the concentration of agent exposure in the gathering and transportation system,the adaptability of the 20#carbon steel(without internal anti-corrosion)using in gathering and transportation pipeline currently is not clear for the future produced liquid.To investi-gate the corrosion behavior of 20#carbon steel in the produced fluid,according to the concentration prediction of the alkali-free composite flooding ternary return produced fluid provided by a production capacity construction project in a certain block of Daqing Oilfield,based on the indoor simulation of the on-site gathering and transportation system working conditions,the corrosion behavior of 20#car-bon steel in alkali-free composite flooding simulated produced fluid is clarified through dynamic corro-sion simulation tests and electrochemical tests.The results show that the corrosion rate of 20#carbon steel specimen in the simulated solution with the highest concentration is relatively high,and the corro-sion grade is moderate,while the corrosion grade in the current produced liquid and remixed water is low.There is obvious passivation phenomenon on the surface of the specimen,as Cl-could quickly penetrate the passivation film,resulting in a short passivation time,and accelerating the corrosion elec-trode reaction.Considering the large amount of Cl-present in the gathering and transportation pipeline in the future,the electrochemical reaction becomes more complex,which will result in the aggrava-tion of the corrosion in the pipeline.Therefore,it is recommended to take appropriate internal corro-sion protection measures in gathering and transportation pipelines.

20#carbon steelalkali-free composite floodingsimulated produced liquidcorrosion behavior

王天祥、朱玉明

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大庆油田设计院有限公司

塔里木油田公司

20#碳钢 无碱复合驱 模拟采出液 腐蚀行为

2024

油气田地面工程
大庆油田有限责任公司

油气田地面工程

影响因子:0.273
ISSN:1006-6896
年,卷(期):2024.43(10)
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