首页|还原性离子对聚合物黏损的影响及防治方法的研究

还原性离子对聚合物黏损的影响及防治方法的研究

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杏北油田三采区块呈现分布广、开发周期叠加、调水难度较大等特点,受生产废液、三采水回注等影响,注入水质中还原性离子浓度较高,还原性离子氧化还原反应过程产生强氧化性的氧自由基,对聚合物黏损影响较大.为了改善稀释水质还原性影响,提高开发效果,通过研究还原性离子浓度与聚合物黏度的影响关系,明确了聚合物驱注入水质还原性离子质量浓度应低于 1.0 mg/L,并针对还原性离子的防治方法开展了不同曝氧工艺应用效果对比,明确了以强制曝氧工艺为主、硫化物去除剂加药工艺为辅的工艺组合方式,同时为预防曝氧过量对地面系统设备产生腐蚀风险,开展了溶解氧浓度与腐蚀速率的影响关系研究.研究结果表明:溶解氧质量浓度控制在5.5 mg/L以下时,腐蚀速率能够保持在轻度腐蚀标准以内,对地面设备管线腐蚀影响较小,该研究对油田聚合物驱开发方式下的黏损治理具有一定的借鉴意义.
Research on the Effect of Reducing Ions on Polymer Adhesion and Prevention Methods
The ASP production block of Xingbei Oilfield is characterized by wide distribution,superimposed development cycle,and relatively difficult water transfer,etc.Therefore,affected by production waste liquid and re-injection of ASP produced water,the content of reducing ions in injected water is high,and the REDOX reaction process of reducing ions produces strong oxidizing oxygen free radicals,which has a great impact on polymer viscosity loss.In order to improve the reducing influence of dilution water quality and improve development effect,by studying the relationship between the reducing ion content and polymer viscosity,it is clarified that the reducing ion content index of polymer flooding water quality should be lower than 1.0 mg/L.Besides,the application effects of different oxygen aeration processes are compared according to the control methods of reducing ions,and the process combination with forced oxygen aeration as the main process and sulfide remover dosing process as the auxiliary process is established.At the same time,in order to prevent the corrosion risk caused by excessive oxygen aeration on the ground system equipment,the relationship between the dissolved oxygen content and the corrosion rate is studied.The results show when the dissolved oxygen content is controlled below 5.5 mg/L,the corrosion rate can be kept below the standard of mild corrosion,and the impact on the corrosion of the ground equipment pipeline is small.It has a certain reference significance for the treatment of viscosity loss under the development mode of oilfield polymer flooding.

reductivitypolymer viscosityfree radical reactionoxygen aeration process

张守伦

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大庆油田有限责任公司第四采油厂

还原性 聚合物黏度 自由基反应 曝氧工艺

2024

油气田地面工程
大庆油田有限责任公司

油气田地面工程

影响因子:0.273
ISSN:1006-6896
年,卷(期):2024.43(12)