仪器仪表学报2024,Vol.45Issue(7) :218-226.DOI:10.19650/j.cnki.cjsi.J2412721

LIBS结合ASG-LWNet的煤中有机元素定量分析

Laser-induced breakdown spectroscopy combined with ASG-LWNet for quantitative analysis of organic elements in coal

彭庆澳 易辉 郑磊
仪器仪表学报2024,Vol.45Issue(7) :218-226.DOI:10.19650/j.cnki.cjsi.J2412721

LIBS结合ASG-LWNet的煤中有机元素定量分析

Laser-induced breakdown spectroscopy combined with ASG-LWNet for quantitative analysis of organic elements in coal

彭庆澳 1易辉 1郑磊1
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作者信息

  • 1. 南京工业大学电气工程与控制科学学院 南京 211816
  • 折叠

摘要

针对LIBS在煤质检测中受到基体效应或环境因素的干扰导致定量分析准确度降低的问题,本文提出一种基于激光诱导击穿光谱结合ASG-LWNet的方法,用于快速准确定量分析煤中有机元素.首先,利用激光诱导击穿光谱仪对34组煤质样品的LIBS光谱进行采集;然后,采用自适应SG滤波算法对采集后的光谱去噪,不断更新滤波器参数以适应不同的信号特性,以获得更好的滤波效果;最后,筛选C、H和S 3种元素的对应特征谱线输入LWNet模型作定量分析.实验表明,基于ASG-LWNet模型的C、H和S元素在测试集上的相关决定系数(R2)分别为0.998 4、0.973 2和0.995 4,均方根误差(RMSE)分别为0.379 4、0.217 9和0.611,与未经去噪前相比,预测精度显著提高.结果表明,在光谱噪声复杂的情况下,该方法能够降低基体效应的影响,提高定量分析的准确度.

Abstract

To address the issue of low accuracy in quantitative analysis of coal quality testing using laser-induced breakdown spectroscopy(LIBS)due to matrix effects or environmental factors,this article proposes a method for fast quantitative analysis of organic elements in coal based on LIBS technology combined with the ASG-LWNet algorithm.Firstly,the LIBS spectra of 34 coal samples are collected using a laser-induced breakdown spectroscopy instrument.Then,an adaptive SG filtering algorithm is used to denoise the collected spectra,continuously updating the filter parameters to adapt to different signal characteristics and achieve better filtering effects.Finally,the corresponding characteristic spectral lines of the elements C,H,and S are selected as inputs to the LWNet model for quantitative analysis.Experimental results show that the correlation coefficients of C,H,and S elements based on the ASG-LWNet model on the test set are 0.998 4,0.973 2,and 0.995 4,respectively.And the root mean square errors are 0.379 4,0.217 9,and 0.611,respectively.Compared with before denoising,the prediction accuracy is significantly improved.The results indicate that,in the case of complex spectral noise,this method can reduce the impact of matrix effects and improve the accuracy of quantitative analysis.

关键词

激光诱导击穿光谱/煤质/自适应滤波/线性加权网络

Key words

laser-induced breakdown spectroscopy/coal quality/adaptive filtering/linear weighted network

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出版年

2024
仪器仪表学报
中国仪器仪表学会

仪器仪表学报

CSTPCD北大核心
影响因子:2.372
ISSN:0254-3087
参考文献量8
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